Dye sensitized photographic imaging system

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430286, 430287, 430919, 430920, 522 25, G03C 172

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active

047435313

ABSTRACT:
A photographic imaging system is disclosed comprised of an imaging dye or a precursor thereof, a hardenable organic component containing ethylenic unsaturation sites and capable of imagewise modulating mobility of the dye or dye precursor as a function of addition at the sites of ethylenic unsaturation, and coinitiators for ethylenic addition. The coinitiators include an azinium salt activator and a photosensitizer which is a dye exhibiting a reduction potential which in relation to that of said ionized azinium salt activator is at most 0.1 volt more positive, with the further proviso that, when the photosensitizer is a keto dye having its principal absorption peak at a wavelength shorter than 550 nm, it exhibits when excited by imaging radiation an intersystem crossing efficiency to a triplet state of less than 10 percent.

REFERENCES:
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patent: Re27925 (1974-02-01), Jenkins et al.
patent: 4289842 (1981-09-01), Tan et al.
patent: 4399209 (1983-08-01), Sanders et al.
patent: 4440846 (1984-04-01), Sanders et al.
patent: 4497889 (1985-02-01), Fuerniss
patent: 4590147 (1986-05-01), Lindley
Research Disclosure, vol. 200, Dec. 1980, Item 20036.
Specht, Martic, and Farid, "A New Class of Triplet Sensitizers", Tetrahedron, vol. 38, pp. 1203-1211, 1982.

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