Dual damascene process

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S624000, C438S638000, C438S700000, C438S738000

Reexamination Certificate

active

06391757

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a dual damascene process, and more particularly, to a dual damascene process that combines low-K materials and Cu.
2. Description of the Prior Art
To satisfy requirements for high integration and high speed in integrated circuits (ICs), especially in a deep sub-micro (<0.18 &mgr;m) semiconductor process, a Cu dual damascene process is now becoming a more widely used and a standard process in forming an interconnection line within the inter-metal dielectric layer of low dielectric constant (low k) materials. Since Copper has both a low resistance and a low electromigration resistance, the low k materials are useful in improving the RC delay effect of a metal interconnection.
Please refer to
FIG. 1
of a cross-sectional diagram of a semiconductor wafer
10
with a typical dual damascene structure
11
. As shown in
FIG. 1
, the dual damascene structure
11
formed within a dielectric layer
20
is composed of a via
22
and a trench
23
. A conductive layer
14
is formed in the dielectric layer
12
beneath the via
22
, and a Cu conductive layer
24
fills the trench
23
. The Cu conductive layer
24
and the conductive layer
14
are connected by a via plug
22
a
penetrating through the passivation layer
18
between the dielectric layer
12
and the dielectric layer
20
.
To prevent a diffusion of Cu from the dual damascene structure
11
into the adjacent dielectric layer
20
, a barrier layer
25
is needed on a surface of the dual damascene structure
11
according to the prior art. Commonly, the barrier layer
25
comprises the following properties: (1) good exclusion of the diffusing atoms, (2) good adhesion to Cu and the dielectric layer, (3) proper resistance (<1000 &mgr;&OHgr;-cm), and (4) good step coverage. Usually Ti, TiN, TaN, WN, etc. are used to form the barrier layer.
However, failure such as a via open normally occurs in the prior Cu dual damascene process. Cu diffuses from the cracks in the barrier layer
25
into the dielectric layer
20
, which results in a disconnection problem between the Cu conductive layer
24
and the conductive layer
14
. The situation is worsened when the dielectric layer
20
is composed of a low k material with a high thermal expansion coefficient, such as a SiLK™ or a porous structure material. In a dual damascene process of a SILK™ dielectric layer
20
and a TaN barrier layer
25
, the thermal expansion coefficients of the SILK™, Cu and TaN are 60 ppm/°C., 17 ppm/°C. and 3 ppm/°C., respectively. The TaN barrier layer
25
with the least thermal expansion coefficient is subject to a thermal stress produced from the SiLK™ dielectric layer
20
, thus producing cracking. As a result, via failure is induced.
SUMMARY OF THE INVENTION
It is therefore a primary objective of the present invention to provide a dual damascene process to solve the above-mentioned problems.
In a preferred embodiment of the present invention, the dual damascene process first provides a semiconductor wafer comprising a substrate and a conductive layer positioned on the substrate. A first passivation layer, a first dielectric layer and a second passivation layer are respectively formed on the substrate of the semiconductor wafer. Following that, a first lithography and etching process is performed to form at least one via hole in the second passivation layer and the first dielectric layer. Thereafter, a second dielectric layer and a third passivation layer are respectively formed on the surface of the semiconductor wafer with the second dielectric layer filling the via hole. A second lithography and etching process is then performed to form at least one trench in the third passivation layer and the second dielectric layer. The trench and the via hole together construct a dual damascene structure. Finally, a barrier layer and a metal layer are respectively formed on the surface of the semiconductor wafer with the metal layer filling the dual damascene structure, and a chemical-mechanical-polishing (CMP) process is performed to complete the dual damascene process.
The present invention uses a hard dielectric material to form a via hole of the dual damascene structure and uses a low-K material to form a trench of the dual damascene structure. Therefore, the dual damascene structure has enough compression resistance to avoid structure deformation and a via open issue, and also produces a low RC delay effect.
These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment, which is illustrated in the various figures and drawings.


REFERENCES:
patent: 5741626 (1998-04-01), Jain et al.
patent: 5887076 (1999-03-01), Dai
patent: 5935762 (1999-08-01), Dai et al.
patent: 6004188 (1999-12-01), Roy
patent: 6103456 (2000-08-01), Tobben et al.
patent: 6184128 (2001-02-01), Wang et al.
patent: 6235628 (2001-05-01), Wang et al.
patent: 6294836 (2001-09-01), Paranjpe et al.
patent: 6323123 (2001-11-01), Liu et al.
patent: 2001/0008802 (2001-07-01), Nishizawa
patent: 2001/0027003 (2001-10-01), Rangarajan et al.
patent: 2001/0045656 (2001-11-01), Yokoyama

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