Dry etching method

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156643, 156646, 156652, H01L 2100

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active

052214303

ABSTRACT:
Proposed is a method for improving resist selectivity in dry etching of an aluminum-based material layer. A mixed gas containing a chlorine-based gas and hydrogen iodide (HI) is used as an etching gas. The chlorine-based gas furnishes Cl* as a main etchant for the Al-based material layer, while HI furnishes H*. For anisotropic etching of the Al-based material layer, decomposition products of a resist mask are used as a sidewall protection film. It has been known that deposition of the sidewall protection film is promoted when hydrogen atoms are contained in the sidewall protection film. HI is used in the present invention as a supply source for H* because the interatomic bond energy of its H--I bond is low as compared to that of H.sub.2, HCl or HBr so that HI is superior to the H* yielding efficiency under discharge dissociation conditions. In this manner, the bias power necessary for anisotropic etching may be reduced to inhibit sputtering out of the resist mask. Among practically useful etching gases are BCl.sub.3 /Cl.sub.2 /HI and Cl.sub.2 /HI.

REFERENCES:
patent: 4030967 (1977-06-01), Ingrey et al.
patent: 4919748 (1990-04-01), Bredfenner et al.
"Reactive Ion Etching of Piezoelectric Films for Acoustic Wave Devices"; Utrosonic Symposia Proceedings, 1, Abstract, 1982; Wang et al.
"Silicon Processing for the VLSI Era"; vol. 1; by Stanley Wolfe; .COPYRGT.1986; Lattice Press; Sunset Beach, Ca., pp. 559-563.

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