Double-sided capacitor structure for a semiconductor device...

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S254000, C438S396000

Reexamination Certificate

active

06790725

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to the field of semiconductor manufacture and, more particularly, to a double-sided capacitor structure and a method for forming the structure.
BACKGROUND OF THE INVENTION
During the manufacture of semiconductor devices which comprise memory elements, such as dynamic random access memories (DRAMs), static random access memories (SRAMs), and some microprocessors, container capacitors are commonly formed. Container capacitors are well known to allow an increased stored charge over planar capacitors by increasing the surface area on which the charge can be stored. To further increase the surface area on which the charge can be stored, polysilicon storage nodes are commonly converted to hemispherical silicon grain (HSG) polysilicon. This material has a roughened surface compared with non-HSG polysilicon, and therefore an increased surface area on which a charge can be stored.
FIGS. 1-8
depict a conventional method for forming a container capacitor from HSG polysilicon.
FIG. 1
depicts a semiconductor wafer substrate assembly
10
comprising a semiconductor wafer
12
having a plurality of doped areas
14
which allow proper operation of a plurality of transistors
16
. Each transistor comprises gate oxide
18
, a doped polysilicon control gate
20
, silicide
22
such as tungsten silicide to increase conductivity of the control gate, and a capping layer
24
of tetraethyl orthosilicate (TEOS) oxide. Silicon nitride spacers
26
insulate the control gate
20
and silicide
22
from polysilicon pads
28
to which the container capacitors will be electrically coupled. Further depicted in
FIG. 1
is shallow trench isolation (STI, field oxide)
30
which reduces unwanted electrical interaction between adjacent control gates, and a thick layer of deposited oxide
32
such as borophosphosilicate glass (BPSG). A patterned photoresist layer
34
defines the location of the container capacitors to be formed. The
FIG. 1
structure may further include one or more bit (digit) lines under the TEOS layer or various other structural elements or differences which, for simplicity of explanation, have not been depicted.
The
FIG. 1
structure is subjected to an anisotropic etch which removes the exposed portions of the BPSG layer to form a patterned BPSG layer which provides a base dielectric having a recess for the container capacitor. During this etch the polysilicon pads
28
and possibly a portion of TEOS capping layer
24
are exposed as depicted in FIG.
2
. The remaining photoresist layer is stripped and any polymer (not depicted) which forms during the etch is removed according to means known in the art to provide the
FIG. 3
structure.
As depicted in
FIG. 4
, a blanket polysilicon layer
40
is formed conformal with the deposited oxide layer, and will provide a container capacitor storage node for the completed capacitor. A thick blanket filler material
42
, such as photoresist, is formed to fill the containers provided by polysilicon
40
. The
FIG. 4
structure is then subjected to a planarizing process, such as a chemical planarization, a mechanical planarization, or a chemical mechanical planarization (CMP) step. This process removes horizontal portions of the photoresist
42
, the polysilicon
40
, and likely a portion of the BPSG
32
to result in the
FIG. 5
structure.
Next, the BPSG
32
is partially etched with an etch selective to polysilicon (i.e. an etch which minimally etches or, preferably, doesn't etch polysilicon) to result in the structure of FIG.
6
. At this point in the process the polysilicon storage nodes
40
are only minimally supported. The bottom plates
40
in the
FIG. 6
structure each comprise a first region
60
which defines a recess, and a second region
62
which defines an opening to the recess, with the first and second regions being continuous, each with the other. In other words, the bottom plate
40
of
FIG. 6
defines a receptacle having a rim
62
which defines an opening to the interior of the receptacle. The regions
60
,
62
form vertically-oriented sides of the bottom plate, and the sides are electrically-coupled by a horizontally-oriented bottom
64
.
After etching the BPSG, a process is performed which converts the smooth polysilicon to HSG polysilicon storage plates
70
as depicted in FIG.
7
. Various processes for converting the smooth polysilicon to HSG polysilicon are known in the art.
After performing the conversion of the smooth polysilicon to HSG polysilicon, a cell dielectric layer
80
, for example a layer of high-quality cell nitride, a polysilicon container capacitor top plate
82
, and a planar oxide layer such as BPSG
84
are formed according to means known in the art to result in the
FIG. 8
structure. Subsequently, wafer processing continues according to means known in the art.
One problem which can result during the process described above is flaking of the HSG polysilicon from the storage node
70
as depicted in FIG.
9
. These loose portions
90
are conductive and thus, when they break off and contact two adjacent conductive structures, can short the structures together and result in a malfunctioning or nonfunctioning device. Typically, the greatest number of such defect occurs at the top of the storage plates. This may occur as these ends are not protected by adjacent structures. This may also occur because as wafer processing continues the tops are the most likely portion of the storage plate to be contacted during a CMP or other step, and also incur the highest stresses.
Another problem which can occur with the process described above results from the very close lateral spacing between adjacent storage plates. As a design goal of semiconductor engineers is to form as many storage capacitors per unit area as possible, and there are typically several million storage capacitors on each memory chip, even a small decrease in spacing between features can allow for the formation of many more features in the same area. Thus the capacitors are formed as close together as wafer processing will allow. As the roughened polysilicon grains grow, grains from two adjacent plates can form a bridge
92
between the two plates and thus short them together to result in a malfunctioning device.
Forming the capacitor structures close together such that there is very little space between adjacent double-sided containers also makes it likely that particles of contamination will be trapped between adjacent containers to result in shorting between the containers. Given the normally tight and deep spaces of the structure, it is difficult or impossible to reliably remove the particles which contaminate the wafer surface with conventional cleaning steps currently available in the field of semiconductor device manufacturing.
A method used to form container capacitor storage plates which reduces or eliminates the problems described above, and a structure resulting therefrom, would be desirable.
SUMMARY OF THE INVENTION
The present invention provides a new method which, among other advantages, reduces problems associated with the manufacture of semiconductor devices, particularly problems resulting during the formation of double-sided capacitor structures (i.e. capacitor structures having the capacitor top plate formed on two sides of the bottom plate, the inside and the outside of the container, as depicted in FIG.
8
). In accordance with one embodiment of the invention an opening is provided in an oxide layer and a first continuous polysilicon layer is formed within the opening. The first polysilicon layer is planarized, for example using a mechanical or chemical mechanical polishing (CMP) process. The first polysilicon layer, which will form a portion of the capacitor top plate, is then etched to form a plurality of recesses therein.
After forming the plurality of recesses in the first polysilicon layer, a blanket cell dielectric layer and a blanket second polysilicon layer are formed within the recesses. The second polysilicon and the cell dielectric are cleared from horizontal surfa

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