Device fabrication process

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Forming nonplanar surface

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430326, 430330, G03C 500

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active

053668510

ABSTRACT:
The sensitivity and dry etching pattern control of chemically amplified resists used in the production of devices such as electronic devices is substantially enhanced while image quality is improved through use of a specific expedient. In particular, the resist material after coating on the device substrate, is treated, e.g., heated to sufficiently high temperatures, to remove a portion of the protective groups on the polymeric component of the resist. Generally, when removal up to approximately 90% of the protective groups for substituents such as t-butoxycarboxyl is effected through this procedure, sensitivities as good as 10 mJ/cm.sup.2 for an X-ray exposure (.lambda.=14.ANG.) have been achieved, and both the image quality and dry etching pattern control are improved.

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R. G. Tarascon et al., Polymer Engineering and Science, 29, 850 (1989).
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Reichmanis: Chemistry of Materials, 1991, 3, pp. 394-407.
Novembre: Proceedings SPIE, 1991, 1466, pp. 89-95.

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