Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Forming nonplanar surface
Reexamination Certificate
1999-08-05
2001-05-22
Le, Hoa Van (Department: 1752)
Radiation imagery chemistry: process, composition, or product th
Imaging affecting physical property of radiation sensitive...
Forming nonplanar surface
C430S330000, C430S030000
Reexamination Certificate
active
06235452
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Technical Field
The invention relates generally to semiconductor processing, and more specifically, to detecting gaseous substances emanating from material used in semiconductor processing.
2. Background Art
In semiconductor processing, certain materials, such as resists of polymeric composition, may produce and emit a gaseous substance when irradiated or thermolyzed. If the gaseous substance is corrosive and/or present in a certain quantity, the substance may be damaging to the materials surrounding the resist. For example, when exposed to ultraviolet light, a negative resist used in masking a semiconductor device may produce and emit minute quantities of hydrochloric acid. Hydrochloric acid, when reaching a certain strength and when within a particular proximity to the lens in a stepper chamber, may corrode the magnesium coatings on the lens, thus damaging the lens. Although the quantity of the hydrochloric acid emitted from the resist may be minute, an accumulation of acid after a period of time may eventually accumulate to a corrosive amount.
Within the technology of lithography, acids may be detected on an exposed film or surface through the use of an indicating dye, which is in contact with the exposed film or surface. Examples of this type of acid detection are found in the following U.S. Patents: U.S. Pat. No. 5,441,850, “Imaging Medium and Process for Producing an Image,” issued to Marshall et al.; U.S. Pat. No. 5,514,519, “Production of Three-Dimensional Objects,” issued to Neckers; and U.S. Pat. No. 5,631,118, “Imaging Medium,” issued to Gaudiana et al.
Although acids can be detected on a surface as described in the above-referenced patents, the patents do not disclose, nor recognize the need for, the detection of acids that are in a gaseous state, and the detection of such gaseous acids at a location that is spatially disposed from the exposed film or surface. Also, the above-referenced patents do not take in account the corrosive and cumulative effects of gaseous substances involved in semiconductor processes. Indeed, most acids detected in lithographical systems and tests therefor are not relevant in semiconductor processes.
SUMMARY OF THE INVENTION
It is thus an advantage of the present invention to provide a method for detecting gaseous substances emanating from material used in semiconductor processing
The advantages of the present invention are realized by a method of detecting an evolving or diffusing gaseous substance emanating from an irradiated or thermolyzed layer of polymeric composition. The method includes spatially disposing from the irradiated or thermolyzed layer a detector layer which includes a compound having leaving groups that are sensitive to the substance being detected. In the preferred embodiment, the evolving or diffusing gaseous substance is confined through the irradiated or thermolyzed layer of polymeric composition, the detector layer and non-reactive spacer elements.
Another advantage of the present invention is detecting the quantity of the evolving or diffusing gaseous substance emanating from the irradiated or thermolyzed layer of polymeric composition.
Generally, the present invention provides a method comprising the steps of: providing a layer of polymeric composition; providing a detector layer having leaving groups that are sensitive to predetermined gaseous substances; spatially disposing said layer of polymeric composition from said detector layer; and detecting evolving or diffusing said gaseous substances emanating from said layer of polymeric composition with said leaving groups of said detector layer.
The present invention additionally provides an apparatus comprising: a layer of polymeric composition; a detector layer having leaving groups that are sensitive to predetermined gaseous substances for detecting evolving or diffusing said gaseous substances emanating from said layer of polymeric composition; and a non-reactive spacer element for spatially disposing said layer of polymeric composition from said detector layer.
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Collins James Patrick
MacDowell Laird Chandler
Moreau Wayne Martin
Santarelli Michael
Clarke Yvette M.
International Business Machines - Corporation
Le Hoa Van
Sabo William D.
Schmeiser Olsen & Watts
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