Cladded silver and silver alloy metallization for improved...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S686000, C438S688000, C257SE21575

Reexamination Certificate

active

07446037

ABSTRACT:
In semiconductor integrated circuit and device fabrication interconnect metallization is accomplished by a clad Ag deposited on a SiO2 level on a Si surface. The clad Ag has a layer of an alloy of Ag and Al (5 atomic %) contacting the SiO2, a layer of substantially pure Ag and an outer layer of the Ag and Al alloy. The alloy improves adhesion to the SiO2, avoids agglomeration of the Ag, reduces or eliminates diffusion at the SiO2 surface, reduces electromigration and presents a passive exterior surface.

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patent: 6100194 (2000-08-01), Chan et al.
patent: 6486514 (2002-11-01), Jeong et al.
Kim, H.C. et al.“Improvement of the thermal stability of silver metallization,” J. App. Phys. vol. 94, No. 8, Oct. 15, 2003, pp. 5393-5395.
Nguyen, P. et al. “Novel technique to pattern silver using CF4 and CF4/O2 glow discharges,” J. Vac. Sci. Technol. B 19(1), Jan./Feb. 2001, pp. 158-165.
Kim, H.C. et al. “Comparison of texture evolution in Ag and Ag(Al) alloy thin films on amorphous SiO2,” J. App. Phys. vol. 95, No. 9 May 1, 2004, pp. 5180-5188.
Hauder, M. et al., “Scaling properties and electromigration resistance of sputtered Ag metallization lines,” Feb. 5, 2001, 838-840, Applied Physics Ltrs vol. 78 No. 6.

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