Barrier coating compositions containing fluorine and methods...

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

Reexamination Certificate

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C430S914000, C430S287100, C430S281100, C430S322000, C430S449000, C526S281000, C526S271000, C522S121000, C522S125000, C522S114000

Reexamination Certificate

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07468235

ABSTRACT:
Provided are a barrier coating composition and a method of forming photoresist pattern by an immersion photolithography process using the same. The barrier coating composition includes a polymer corresponding to formula I having a weight average molecular weight (Mw) of 5,000 to 100,000 daltons and an organic solvent,wherein the expressions 1+m+n=1; 0.1≦1/(1+m+n)≦0.7; 0.3≦m/(1+m+n)≦0.9; and 0.0≦n/(1+m+n)≦0.6 are satisfied; Rf is a C1to C5fluorine-substituted hydrocarbon group; and Z, if present, includes at least one hydrophilic group. Compositions according to the invention may be used to form barrier layers on photoresist layers to suppress dissolution of photoresist components during immersion photolithography while allowing the barrier layer to be removed by alkaline developing solutions.

REFERENCES:
patent: 5445919 (1995-08-01), Wakata et al.
patent: 6277538 (2001-08-01), Choi et al.
patent: 6517990 (2003-02-01), Choi et al.
patent: 2004/0259025 (2004-12-01), Barclay et al.
patent: 2005/0042554 (2005-02-01), Dierichs et al.
patent: 2005/0202351 (2005-09-01), Houlihan et al.
patent: 2005-099646 (2005-04-01), None
patent: 2005-099648 (2005-04-01), None
Ralph R. Dammel et al.,193 nm Immersion Lithography—Taking the Plunge, J. of Photopolymer Science and Technology, 2004, vol. 17, No. 4, pp. 587-602.

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