Active electrostatic seal and electrostatic vacuum pump

Electricity: electrical systems and devices – Electric charge generating or conducting means – Use of forces of electric charge or field

Reexamination Certificate

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C361S233000

Reexamination Certificate

active

06538873

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to active electrostatic seals and electrostatic vacuum pumps and, more particularly, to devices and methods wherein gas is transported between closely spaced or contacting surfaces of arbitrary shape. The devices and methods of the invention may be utilized in electrostatic wafer clamps for retaining a coolant gas, in face seals and in shaft seals, but are not limited to such uses.
BACKGROUND OF THE INVENTION
In the fabrication of integrated circuits, a number of well-established processes involve the application of ion beams to semiconductor wafers in vacuum. These processes include, for example, ion implantation, ion beam milling and reactive ion etching. In each instance, a beam of ions is generated in a source and is directed with varying degrees of acceleration toward a target wafer. Ion implantation has become a standard technique for introducing conductivity-altering impurities into semiconductor wafers. A desired impurity material is ionized in an ion source, the ions are accelerated to form an ion beam of prescribed energy and the ion beam is directed at the surface of the wafer. The energetic ions in the beam penetrate into the bulk of the semiconductor material and are embedded in the crystalline lattice of the semiconductor material to form a region of desired conductivity.
The wafer mounting site is a critical part of an ion implantation system. The wafer mounting site is required to firmly clamp a semiconductor wafer in a fixed position for ion implantation and, in most cases, to provide cooling of the wafer. In addition, means must be provided for exchanging wafers after completion of ion implantation. In commercial semiconductor processing, a major objective is to achieve a high throughput in terms of wafers processed per unit time. One way to achieve high throughput is to use a high current ion beam so that the implantation process is completed in a shorter time. However, large amounts of heat are likely to be generated by the high current ion beam. The heat can result in uncontrolled diffusion of impurities beyond prescribed limits in the wafer and in degradation of patterned photoresist layers. Accordingly, it is usually necessary to provide wafer cooling in order to limit the maximum wafer temperature to about 100° C., and limiting the maximum wafer temperature to less than 100° C. may be required in the future.
A number of techniques for clamping a semiconductor wafer at the target mounting site are known in the art. One known technique involves the use of electrostatic forces. A dielectric layer is positioned between a semiconductor wafer and a conductive support plate. A voltage is applied between the semiconductor wafer and the support plate, and the wafer is clamped against the dielectric layer by electrostatic forces. An electrostatic wafer clamp is disclosed by G. A. Wardly in “Electrostatic Wafer Chuck for Electron Beam Microfabrication”,
Rev. Sci. Instrum.,
Vol. 44, No. 10, October 1972, pp. 1506-1509 and in U.S. Pat. No. 3,993,509 issued Nov. 23, 1976 to McGinty. Electrostatic wafer clamp arrangements which utilize a thermally-conductive material to remove heat from the wafer are disclosed in U.S. Pat. No. 4,502,094, issued Feb. 26, 1985 to Lewin et al., U.S. Pat. No. 4,665,463, issued May 12, 1987 to Ward et al., and U.S. Pat. No. 4,184,188, issued Jan. 15, 1980 to Briglia. The Briglia patent discloses a support plate having layers of thermally-conductive, electrically-insulative RTV silicone. Electrostatic wafer clamps are also disclosed in U.S. Pat. No. 4,480,284, issued Oct. 30, 1984 to Tojo et al., U.S. Pat. No. 4,554,611, issued Nov. 19, 1985 to Lewin, U.S. Pat. No. 4,724,510, issued Feb. 9, 1988 to Wicker et al. and U.S. Pat. No. 4,412,133, issued Oct. 25, 1983 to Eckes et al.
An electrostatic wafer clamp that provides highly satisfactory performance is disclosed in U.S. Pat. No. 4,452,177, issued Sep. 19, 1995 to Frutiger. A six-phase electrostatic wafer clamp includes a platen having six sector-shaped electrodes. Voltages with six different phases are applied to the electrodes, with the voltages applied to electrodes on opposite sides of the platen being one-half cycle out of phase. The applied voltages are preferably bipolar square waves.
As indicated above, wafer cooling is typically required during ion implantation. The technique of gas conduction has been utilized for wafer cooling in vacuum. A coolant gas, introduced into a region between the semiconductor wafer and the clamping surface, provides thermal coupling between the wafer and a heat sink. Gas conduction in an electrostatic wafer clamp is disclosed in the aforementioned U.S. Pat. No. 5,452,177.
Wafer clamps which employ gas conduction cooling typically employ means for retaining the coolant gas in the region between the wafer and the clamping surface and thereby limiting leakage of the gas into the vacuum chamber. Such leakage reduces cooling effectiveness and contaminates the vacuum chamber.
Several prior art techniques have been utilized for retaining the coolant gas. One approach uses a perimeter seal, such as an O-ring or a lip seal, at the perimeter of the clamping surface, as disclosed for example in the aforementioned U.S. Pat. No. 5,452,177. The sealing surface comes into contact with the perimeter of the wafer, sealing against the wafer. However, the perimeter seal can easily become damaged, since it is exposed on the clamping surface. The perimeter seal may lose effectiveness easily, becoming contaminated over time with the particulates that are inevitable in process chambers. Particles may be generated by the seal rubbing against the wafer. The rough back side of the silicon wafer itself may compromise the seal. Even when the seal is not compromised, an elastomeric seal is permeable to hydrogen, helium and the lighter gases. Further, an elastomeric seal suffers from compression set and degradation due to harsh processing environments such as radiation and/or severe chemicals.
Another approach to retaining the coolant gas utilizes an area seal, where the wafer is electrostatically clamped against a polished platen surface, providing a minimal clearance between the platen and the wafer, and limiting gas leakage. An area seal produced by the electrostatic clamping of a wafer against a flat and finely polished clamping surface is more resistant to damage than the perimeter seal. However, the area seal may be somewhat more susceptible to leakage due to trapped particles which increase the space between the wafer and the clamping surface. This drawback may be alleviated somewhat by the flexibility of the wafer, and the edge of the wafer may seal around the perimeter despite particles trapped toward the center. However, the increased gas pressure required for adequate cooling requires increased clamping voltage to maintain the wafer clamped against the clamping surface. Typically, as the coolant gas pressure increases, the leak rate also increases.
Another technique for limiting coolant gas leakage into the vacuum chamber utilizes an annular groove around the periphery of the clamping surface. The groove is connected to a vacuum pump, and the coolant gas is removed before it leaks into the vacuum chamber. See, for example, U.S. Pat. No. 4,603,466, issued Aug. 5, 1986 to Morley. This approach has the disadvantages of reduced clamping force in the case of an electrostatic wafer clamp and reduced cooling in the region of the annular groove.
The above-identified problem of gas leakage from the periphery of an electrostatic wafer clamp is an example of a more general sealing problem which involves the leakage of gas between two closely spaced or contacting surfaces of arbitrary shape. Another example of the sealing problem occurs in a shaft seal wherein a shaft extends through a wall from a region of higher pressure to a region of lower pressure. The surfaces cannot be permanently sealed, such as with an adhesive, because of relative movement between the surfaces. In the case of the electrostatic wafer clamp, the wafer is remove

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