Non-volatile semiconductor memory device and manufacturing...

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S257000, C438S266000, C257S326000

Reexamination Certificate

active

06673678

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Industrial Applicability
The present invention relates to a method of manufacturing a non-volatile semiconductor memory device for storing information by accumulation of an electric charge. More specifically, the present invention relates to a method of manufacturing a non-volatile semiconductor memory device in which a memory element is selectively activated by a field effect transistor, and to the non-volatile semiconductor memory device manufactured by accordance with this method.
2. Description of the Background Art
As a non-volatile semiconductor memory device having memory elements provided with floating gates and control gates, flash memory can be mentioned as an example. A variety of designs are available for flash memories, one of which is a device in which a memory element is selectively activated by a field effect transistor. A flash memory with such a configuration has been disclosed, for example, in Japanese Patent Application Laid-Open No. 6-275847/1994. In the following, a method of manufacturing the flash memory disclosed in Japanese Patent Application Laid-Open No. 6-275847/1994 is described with reference to
FIGS. 44
to
52
.
As shown in
FIG. 44
, on a principal surface of a semiconductor substrate
200
, a silicon oxide layer
202
as a tunnel oxide layer is grown, and then a polysilicon layer
204
as a floating gate is formed. Part of the polysilicon layer
204
that is positioned over an access transistor formation region
232
is selectively etched as shown in
FIG. 45
, and remaining part of the polysilicon layer
204
positioned over a memory element formation region
234
is left. This remaining part of the polysilicon layer
204
is hereinafter referred to as a polysilicon layer
204
a.
As shown in
FIG. 46
, an ONO-layer
206
is formed on the polysilicon layer
204
a,
and a silicon oxide layer
208
as a gate oxide layer is formed over the access transistor formation region
232
. Subsequently, a polysilicon layer
210
is formed on the ONO-layer
206
and the silicon oxide layer
208
.
As shown in
FIG. 47
, a resist
212
is prepared on the polysilicon layer
210
, which is then selectively etched by using the resist
212
as a mask, thereby forming a gate electrode
214
over the access transistor formation region
232
while leaving part of the polysilicon layer
210
that is positioned over the memory element formation region
234
. The remaining part of the polysilicon layer
210
over the memory element formation region
234
is hereinafter referred to as a polysilicon layer
210
a.
This etching exposes the silicon oxide layer
208
on a principal surface
236
of the semiconductor substrate
200
, in the area between the gate electrode
214
and a floating gate to be formed in a later step. Next, as shown in
FIG. 48
, the resist
212
is removed and a resist
216
is prepared over the memory element formation region
234
and the access transistor formation region
232
. The resist
216
is patterned so that it provides a mask for forming a control gate.
Note that the resist
216
is patterned so that it covers the gate electrode
214
, while at the same time its side surface
216
a
does not overlap the polysilicon layers
204
a
and
210
a.
The gate electrode
214
has to be covered because the gate electrode
214
is formed of a material identical to that of the control gate and the floating gate, i.e. polysilicon, and therefore has to be protected from being etched away during the etching step to form the control gate and the floating gate. The patterning is provided in such a way that the side surface
216
a
does not overlap the polysilicon layers
204
a
and
210
a
because, when the polysilicon layers
204
a
and
210
a
are etched later to form the control gate and the floating gate, unnecessary polysilicon layers
204
a
and
210
a
are left on the principal surface of the semiconductor substrate
200
if the side surface
216
a
overlaps the polysilicon layers
204
a
and
210
a.
Consequently, the resist
216
is patterned while maintaining the silicon oxide layer
208
exposed on a principal surface
236
of the semiconductor substrate
200
, in the area between the gate electrode
214
and a floating gate to be formed in a later step.
The polysilicon layer
210
a
is selectively etched by using the resist
216
as a mask to form a control gate
218
. The ONO-layer
206
is then selectively etched by using the resist
216
as a mask, as shown in FIG.
49
. This etching removes the exposed portion of the silicon oxide layer
208
and exposes the principal surface
236
in the area between the gate electrode
214
and a floating gate to be formed in a later step.
As shown in
FIG. 50
, the polysilicon layer
204
a
is selectively etched by using the resist
216
as a mask, thereby forming a floating gate
220
. Since the principal surface
236
is exposed, the principal surface
236
is also etched to unavoidably form a groove section
222
on the principal surface
236
. Subsequently, an ion implantation is provided on the principal surface of the semiconductor substrate
200
using the resist
216
as a mask, thereby forming a source/drain region
224
in the memory element formation region
234
as well as an impurity region
226
electrically connected to the source/drain region
224
in the groove section
222
.
A silicon oxide layer
228
is grown on the principal surface of the semiconductor substrate
200
as shown in
FIG. 51
, followed by the formation of a contact hole
238
on the silicon oxide layer
228
so that the source/drain region
224
is exposed. As shown in
FIG. 52
, an aluminum wiring layer
230
is then provided on the silicon oxide layer
228
. The aluminum wiring layer
230
is also formed on the contact hole
238
and is electrically connected to the source/drain region
224
. A memory element
242
is provided with the control gate
218
, the floating gate
220
, and the source/drain region
224
, whereas an access transistor
244
is provided with the gate electrode
214
and the source/drain region
240
.
Referring to
FIG. 52
, for selectively activating the memory element
242
with the access transistor
244
, the source/drain region
240
of the access transistor
244
and the source/drain region
224
of the memory element
242
are electrically connected through the impurity region
226
formed within the groove section
222
. Since the wiring region comprising the source/drain region
240
, the impurity region
226
, and the source/drain region
224
has an irregular shape due to the presence of the groove section
222
, the diffusion resistance of the impurity region
226
significantly affects the diffusion. resistance of the wiring region. In the meantime, as described with reference to
FIG. 50
, the source/drain region
224
and the impurity region
226
are formed simultaneously by a single ion implantation. Since this implantation is performed under the conditions for depth and concentration of impurities required for forming the source/drain region
224
, the depth and concentration of impurities at the impurity region
226
are not at the adequate levels required for the region. This leads to undesirable consequences where, for example, a high diffusion resistance at the impurity region
226
slows the speed of programming, erasing, and reading of the memory element
242
.
SUMMARY OF THE INVENTION
The present invention has been made to eliminate the above-described problems with the prior art. Accordingly, an object of the present invention is to provide a non-volatile semiconductor memory device and a manufacturing method thereof, wherein at least one of either the source/drain region of the access transistor or source/drain region of the memory element can be formed with a required thickness and concentration of impurity, and also the diffusion resistance of the impurity region formed at the groove section can be lowered.
The present invention provides a manufacturing method of a non-volatile semiconductor memory device comprising: at least o

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