Semiconductor device and method of manufacturing the same

Semiconductor device manufacturing: process – Making field effect device having pair of active regions... – Having insulated gate

Reexamination Certificate

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C438S282000, C438S305000, C438S306000, C438S526000, C257S339000, C257S607000

Reexamination Certificate

active

06380036

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and a method of manufacturing the same, and in particular, to a semiconductor device having a field-effect transistor and a method of manufacturing the same.
2. Description of the Background Art
In recent years, semiconductor devices typically including an SRAM (Static Random Access Memory) and a DRAM (Dynamic Random Access Memory) have been highly integrated to have such a structure that each chip includes many elements. Among these elements, a majority of transistors are field-effect transistors called MOSFETs (Metal Oxide Semiconductor Field Effect Transistors).
The MOSFETs can be classified into two types having different electric polarities, i.e., an nMOSFET (negative MOSFET) in which electrons flow through a channel region and a pMOSFET (positive MOSFET) in which holes flows. These nMOSPETs and pMOSPETs are combined to form various kinds of circuits.
Structures of such transistors can be roughly classified into a surface channel type and a buried channel type. Generally in the CMOS structure which consists of an MOSFET and a pMOSFET on the same substrate, the nMOSFET of the surface channel type and the pMOSFET of the buried channel type are broadly employed because it is necessary to use the same gate electrode material for the nMOSFET and pMOSFET. Structures of the conventional nMOSFET and pMOSFET will be described below.
FIG. 40
is a schematic cross section showing a structure of a conventional nMOSFET. Referring to
FIG. 40
, a silicon substrate
501
is provided at its surface with a boron diffusion region
503
of p-type. A pair of n-type source/drain regions
507
are formed at the surface of boron diffusion region
503
with a predetermined space between each other. A gate electrode
511
is formed at a region located between paired source/drain regions
507
with a gate insulating film
509
therebetween.
Paired n-type source/drain regions
507
, gate insulating film
509
and gate electrode
511
form an nMOSFET
520
of surface channel type.
Side walls of gate electrode
511
are covered with side wall spacer
513
.
FIG. 41
is a cross section schematically showing a structure of a conventional pMOSFET. Referring to
FIG. 41
, a silicon substrate
601
is provided at its surface with a phosphorus diffusion region
603
of n-type. A pair of p-type source/drain regions
607
are formed at the surface of phosphorus diffusion region
603
with a predetermined spaced between each other. A gate electrode
611
is formed at a region located between paired source/drain regions
607
with a gate insulating film
609
therebetween. A p-type buried channel region
615
is formed at the surface of phosphorus diffusion region
603
located between paired source/drain regions
607
.
Paired p-type source/drain regions
607
, gate insulating film
609
, gate electrode
611
and p-type buried channel region
615
form a pMOSFET
620
of buried channel type.
Side walls of gate electrode
611
are covered with side wall spacer
613
.
A method of manufacturing the conventional nMOSFET shown in
FIG. 40
will be described below.
FIGS. 42
to
46
are schematic cross sections showing the process of manufacturing the conventional nMOSFET in accordance with the order of process steps. Referring first to
FIG. 42
, the ordinary LOCOS (Local Oxidation of Silicon) is executed to form isolating oxide films
521
on silicon substrate
501
. In this step, isolating implantation regions
523
under isolating oxide films
521
are formed. Thereafter, a pad oxide film
531
of a predetermined thickness is formed to cover the whole surface.
Referring to
FIG. 43
, boron (B) is implanted into the whole surface. Then, a heat processing is executed to activate and diffuse the implanted boron, so that boron diffusion region
503
is formed at the surface of silicon substrate
501
. Thereafter, pad oxide film
531
is removed, e.g., by etching.
Thereby, the surface of boron diffusion region
503
is exposed as shown in FIG.
44
.
Referring to
FIG. 45
, thermal oxidation is effected, so that a silicon oxide film
509
a
as the gate insulating film is formed on the whole surface.
Referring to
FIG. 46
, patterned gate electrode
511
is formed on the surface of gate insulating film
509
a
. Using gate electrode
511
as a mask, ion implantation or the like is performed to form at the surface paired n-type source/drain regions
507
spaced by a predetermined distance. Then, side wall spacer
513
are formed to cover the side walls of gate electrode
511
.
(a) As transistors are miniaturized to a higher extent, a concentration of impurity generally increases in accordance with a scaling rule. In accordance with this, the impurity concentration at the channel region increases in MOSFET
520
shown in
FIG. 40
, and thus inversion of the surface of channel region is suppressed. This results in increase of a threshold voltage of MOSFET
520
of surface channel type.
(b) If the impurity concentration at the channel region increases in MOSFET
520
, carriers moving in the channel scatter to a higher extent. Therefore, mobility of minority carriers at the channel decreases, so that improvement of the drive performance of transistor cannot be substantially expected.
(c) In the pMOSFET
620
of buried channel type shown in
FIG. 41
, buried channel region
615
is of p-type having the same polarity as source/drain regions
607
, and makes connection between paired p-type source/drain regions
607
. By controlling gate applied voltage, the degree of depletion in buried channel region
615
can be changed for modulating the current flowing through the channel.
However, the depletion layer width formed by the gate electric field is smaller than 50 nm from the substrate surface. Further, the depletion layer at the p-n junction between buried channel region
615
and phosphorus diffusion region
603
expands for only about 50 nm or less toward buried channel region
615
. Therefore, the depth of buried channel region
615
must be smaller than about 100 nm in order to deplete whole buried channel region
615
by the gate voltage.
In general, p-type buried channel region
615
is formed by implantation of boron. Since boron has a small mass and a large diffusion coefficient, it is difficult to form a shallow buried diffusion region, and its depth from the substrate surface exceeds 100 nm due to a heat treatment at a later step. When the depth of buried channel region
615
from the substrate surface exceeds 100 nm, a non-depleted region is formed at buried channel region
615
even if a voltage is applied to gate electrode
611
. In this case, a current which cannot be controlled by gate electrode
611
, i.e., so-called punch-through current is generated.
(d) In pMOSFET
620
, source/drain regions
607
are formed by implantation of boron. As already described, boron has a strong tendency to diffuse. Therefore, it is difficult to suppress diffusion of boron from source/drain regions
607
toward the channel region. Accordingly, a effective channel length decreases, which makes it difficult to miniaturize the transistor structure.
For the above reasons (a)-(d), it is difficult to miniaturize the conventional MOSFET.
SUMMARY OF THE INVENTION
An object of the invention is to provide a transistor structure which can be miniaturized without difficulty.
Another object of the invention is to improve a drive performance of a transistor while allowing miniaturization of a transistor structure.
Yet another object of the invention is to suppress generation of a punch-through current during operation of a transistor even in the case where a transistor structure is miniaturized.
According to one aspect of the invention, a semiconductor device having a field-effect transistor includes a semiconductor substrate, a pair of source/drain regions, a gate electrode, and a nitrogen introduced region. The semiconductor substrate is of a first conductivity type, and has a main surface. The paired source/drain regions are of a se

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