Photoresist compositions

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Forming nonplanar surface

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G03F 730

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active

060371072

ABSTRACT:
The invention provides photoresist compositions comprising a resin binder having acid labile blocking groups requiring an activation energy in excess of 20 Kcal/mol. for deblocking, a photoacid generator capable of generating a halogenated sulfonic acid upon photolysis and optionally, a base additive. It has been found that linewidth variation is substantially reduced when using the halogenated sulfonic acid generator in a process involving a high temperature post exposure bake.

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patent: 5753412 (1998-05-01), Babich et al.
Wallraff et al., "Thermal and acid-catalyzed deprotection kinetics in candidate deep ultraviolet resist materials", J. Vac. Sci. Technol., 12(6), pp. 3857-3862, 1994.
Wallraff et al., "Kinetics of Chemically Amplified Resists", Tenth International Technical Conference, Oct. 31-Nov. 2, 1994, Sponsored by Society of Plastics Engineers, Inc., pp. 11-17, 1994.
Yano et al, AN 123: 354463, Abstract of Proc. SPIE-Int. Soc. Opt. Eng. (1995), 2438, pp. 551-63 Chemical Abstracts, ACS, 1998.

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