Ultrasound treatment of polycrystalline silicon thin films to en

Semiconductor device manufacturing: process – Formation of semiconductive active region on any substrate – Polycrystalline semiconductor

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438149, 438162, H01L 2120, H01L 2136, H01L 2100, H01L 2184

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active

059727829

ABSTRACT:
Ultrasound treatment (UST) of poly-Si thin films on glass substrates is disclosed, for improving properties of such thin films for uses such in thin-film transistor applications. Hydrogenated films subjected to UST showed a strong decrease of the sheet resistivity. UST improves the electrical homogeneity of polycrystalline silicon as confirmed by spatially resolved surface photovoltage mapping. Spatially resolved photoluminescence and contact potential difference mapping confirmed that UST effect is grain boundary related. Studies of hydrogenated thin-film transistors demonstrated remarkable UST induced improvement in transistor characteristics, especially, a reduction of leakage current by as much as one order of magnitude and a shift of the threshold voltage. All these effects are believed to result from UST enhanced hydrogenation of dangling bonds at grain boundaries in polycrystalline silicon films.

REFERENCES:
patent: 5517037 (1996-05-01), Yamamoto
"Non-Contact Real Time Monitoring of Hydrogenation Process by Surface Photovoltage Technique and Enhanced Hydrogenation Due to Ultrasound Treatment in Thin Film Poly--Silicon on Glass", by Ostapenko, et al., Proceedings of International Display Research Conference, (Monterey), Oct. 1994, pp. 299-302.
"Enhanced hydrogenation in polycrystalline silicon thin films using low-temperature ultrasound treatment", by S. Ostapenko, et al., Appl. Phys. Lett. 68 (20), May 13, 1996, pp. 2873-2875.
"Activation of luminescence in polycrystalline silicon thin films by ultrasound treatment", by J. Koshka, et al., Appl Phys. Lett. 69 (17), Oct. 21, 1996, pp. 2537-2539.
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Ultrasound Treatment of CZ-Si with "Ring Defects", by S. Ostapenko, et al., VII-th Symposium on Si Material Science and Technology, (San Francisco), May, 1994, pp. 856-867.
"Mechanism of ultrasound-stimulated changes in photoelectric and luminescence properties of cadmium sulfide", by A. P. Zdebskii, et al., Sov. Phys. Semicond. 20(10), Oct. 1986, pp. 1187-1170.
Ostapenko et al, "Non-contact Real Time Monitoring of Hydrogenation Process by Surface Photovoltage Technique and Enhanced Hydrogenation Due to Ultrasound Treatment in Thin Film Poly-silicon on Glass," Proceedings of International Display Research Confere, Oct. 1994.
Ostapenko et al., "Increasing Short Minority Carrier Diffusion Lengths in Solar-grade Polycrystalline Silicon by Ultrasound Treatment," Appl.Phys.Lett., vol. 65, No. 12, pp. 1555-1557, Sep. 1994.
Ostapenko et al., "Ultrasound Stimulated Dissociation of Fe-B Pairs in Silicon," J.Appl.Phys.77 (10), pp.5458-5460, May 1995.

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