Boron incorporated diffusion barrier material

Semiconductor device manufacturing: process – Introduction of conductivity modifying dopant into... – Ion implantation of dopant into semiconductor region

Reexamination Certificate

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C438S685000

Reexamination Certificate

active

06911381

ABSTRACT:
A diffusion barrier layer comprising TiNxByis disclosed for protection of gate oxide layers in integrated transistors. The diffusion barrier layer can be fabricated by first forming a TiN layer and then incorporating boron into the TiN layer. The diffusion barrier layer can also be fabricated by forming a TiNxBylayer using a TDMAT process including boron. The diffusion barrier layer can also be fabricated by forming a TiNxBylayer using a CVD process. The diffusion barrier layer is of particular utility in conjunction with tungsten or tungsten silicide conductive layers formed by CVD.

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Baker, et al. “Combined X-Ray Photoelectron/auger Electron Spectroscopy/Glaning Angle X-Ray diffraction/Extended X-Ray Absorbtion Fine Structure Investigation of TiBxNy Coatings”, J. Vac. Sci. Technol., A 15(2), pp. 284-291. Mar./Apr. 1997.
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