Alloys or metallic compositions – Rhenium base
Reexamination Certificate
2002-05-03
2004-06-15
Oltmans, Andrew L. (Department: 1742)
Alloys or metallic compositions
Rhenium base
C148S407000, C148S442000
Reexamination Certificate
active
06749803
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to wear-resistant materials and more particularly to wear-resistant alloys derived from refractory metals such as rhenium.
2. Description of the Related Art
Material scientists seek to exploit from available resources, namely those elements of the periodic table of elements, different materials having different characteristics that can be used for a variety of purposes and applications. Consequently, there is a great interest in developing conductors, insulators, soft materials, and hard materials from available substances and materials.
With respect to engines and mechanical components, wear resistance is typically a desired characteristic because it allows materials to last a longer time and users to consequently enjoy a cheaper cost per unit time or reduced operational costs. Even though a part may cost twice as much, it may last four times as long so is then approximately half as expensive as a cheaper part over a given time period.
One particularly useful metal is elemental rhenium. Rhenium has atomic number 75 in the periodic table of elements. It is known as a refractory metal which means it has a very high melting point as compared to other materials. Despite the fact that it has a very high melting point, rhenium is not necessarily wear-resistant. Rhenium metal melts at approximately 5756° F. (3180° C., 3453° Kelvin). However, rhenium begins to oxidize at a much lower temperature, of approximately 1000° F. (538° C., 811° K). Rhenium retains excellent ultrahigh temperature strength of approximately 6-9 Ksi (kips per square inch, 1000 pounds per square inch) at 4000° F. (2204° C., 2477° K). Far before it reaches this temperature, the oxidation temperature of rhenium becomes a factor and the oxidation of rhenium produces a volatile oxide that will continually evaporate from the surface of the rhenium part until the part has entirely vaporized.
This can lead to catastrophic failure as can be readily perceived as the evaporation of a part during operation would be much like the boiling away of a part made of dry ice. However, where oxygen is lacking, rhenium has been shown to retain high strength and to resist severe corrosion and wear both in established literature as well as independent tests. Such properties are present at room temperature operation and remain with rhenium even though the temperatures are elevated.
In prior literature, relevant alloying includes development of phase diagrams for several binary alloys of rhenium as well as rhenium-enhanced alloys such as those based on tungsten where rhenium is added to the matrix to enhance resulting properties. In such prior literature, rhenium has been a part of binary alloys such as in tungsten to increase ductility.
Rhenium has also been studied for its effect on chromium-based alloys. For steel, alloys with chromium are known that alloy the creation of “stainless steel.” When alloyed with chromium in amounts greater than 11%, steel converts from a highly oxidation prone substance to a more corrosion-resistant alloy with the general elimination of rust. Similar concepts are known for use in “super alloys” and corrosion-resistive alloys.
However, the prior art does not well reflect the establishment of oxidation-resistant rhenium-based alloy. Consequently, as there is always a need for better materials and materials having better wear characteristics, the present invention provides a solution to a need that will always be felt for better materials.
Additionally, the art has not well addressed the wear that concentrates at small asperities which are microscopic metal protrusions that generally cause roughness on a surface such as a cast or focused metal. With respect to rhenium-based alloys, wear could be focused on such asperities and such wear would by friction create significant heat that would cause an alloyed rhenium to oxidize and vaporize.
In view of the foregoing disadvantages inherent in the known types of alloys and materials now present in the prior art, there is a need for wear-resistant rhenium-based alloys for use in environments where unalloyed or pure rhenium would be subject to oxidation and/or vaporization.
SUMMARY OF THE INVENTION
The present invention provides a family of new wear-resistant rhenium-based alloys for use in environments where unalloyed or pure rhenium would be subject to oxidation and/or vaporization.
The general purpose of the present invention, which will be described subsequently in greater detail, is to provide better materials for use in mechanically or otherwise stressful operating environments in order to provide better wear characteristics and function which are not anticipated, rendered obvious, suggested, or even implied by any of the prior art alloys, either alone or in any combination thereof.
By way of example only, the present invention is embodied in an alloy that has a refractory metal, particularly rhenium, that is subject to oxidation well below its melting point and well below the temperature at which it loses strength and may strengthen the metal by selective combination. This results in an alloy that better resists oxidation and that may have better (and at least as good) wear characteristics. The refractory metal is combined with other alloying materials, such as metals, that have a strong affinity for oxygen. Such alloying materials include the metals chromium, cobalt, nickel, titanium, thorium, aluminum, hafnium, and related elements on the periodic table. These particular elements are at least somewhat soluble in rhenium, if not completely soluble.
It is believed that such elements protect rhenium by forming an oxide on its surface. Once the oxide has formed on the surface of the alloyed part, further attack by oxygen is prevented by the oxide coating. This is a phenomenon that is well-known with aluminum that oxidizes in oxygen, but once the surface of an aluminum object has oxidized, further oxidation is prevented as oxygen cannot get to the unoxidized aluminum below the oxidized surface layer. Stainless steel also exhibits similar characteristics.
Consequently, those metals or other alloying agents that oxidize to form high boiling point oxides may well aid in the protection of the underlying rhenium alloy.
Using powder metallurgy, and possibly using free form fabrication (FFF) or casting, parts and components can be fabricated from rhenium-based alloys having oxygen-attracting qualities. The use of such techniques may render useful alloys with better wear and lower oxidation characteristics. Other features and advantages of the present invention will become apparent from the following description of the preferred embodiments which illustrate by way of example the principles of the invention.
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Honeywell International , Inc.
Mullen, Esq. Douglas A.
Oltmans Andrew L.
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