Semiconductor memory device having a memory region and a...

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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Details

Other Related Categories

C257S315000, C257S324000, C257S326000

Type

Reexamination Certificate

Status

active

Patent number

06770932

Description

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATION
This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No.2002-201997, filed Jul. 10, 2002, the entire contents of which are incorporated herein by reference.
BACKGROUND OF THE INVENTION
1. Field of the Invention
This present invention relates to a semiconductor memory device and a manufacturing method thereof, for example, a nonvolatile semiconductor memory device and its manufacturing method that are suitable for high integrality.
2. Description of the Related Art
We will explain about a structure of a conventional nonvolatile semiconductor memory device.
FIG. 38
shows a schematic top view of the conventional nonvolatile semiconductor memory device.
FIG. 38
a
shows a region where memory cells that are MOS transistors having a floating gate respectively are arranged in an array form, hereinafter, referred to a memory cell region.
FIG. 38
b
shows a region where MOS transistors that have no floating gate and control the memory cells are arranged, hereinafter, referred to a peripheral region.
Generally, the memory cell region is formed with high density in order to achieve high capacity and integrity. Therefore, the peripheral region referred by
FIG. 38
b
is formed with lower density compared to the memory cell region.
As shown in
FIG. 38
a
, in the memory cell region, element regions
161
where memory cells are formed and element isolation regions
162
that separate each of the element regions
161
with each other are arranged in a stripe shape. One of the element regions
161
includes a plurality of memory cells in a horizontal direction of the
FIG. 38
a
. In a direction perpendicular to the element regions
161
, gate connection lines
163
that connect each control gates (not shown) with each other are arranged in a stripe shape.
Floating gates (not shown) are arranged in each of intersected portions between the gate connection line
163
and the element region
161
. A semiconductor substrate under each of the floating gates works as channel region (not shown). Diffusion layers (not shown) that are used as source or drain regions are arranged in the semiconductor substrate adjacent to the channel region. Each of contact layers
164
is electrically connected to one of the diffusion layers.
FIG. 38
b
shows a peripheral region. As shown in
FIG. 38
b
, element regions
171
and element isolation regions
172
that electrically separate each of the element regions
161
with each other are arranged in a stripe shape. In a direction perpendicular to the element regions
171
, gate connection lines
173
that connect each of gate electrodes (not shown) with each other are arranged in a stripe shape.
Gate electrode regions (not shown) are arranged in each of intersected portions between the gate connection line
173
and the element region
171
. A semiconductor substrate under each of the gate electrode regions works as channel region (not shown). Diffusion layers (not shown) that are used as source or drain regions are arranged in the semiconductor substrate adjacent to the channel region. Each of contact layers
174
is electrically connected to one of the diffusion layers. Each of contact layers
175
is electrically connected to one of the diffusion layers. In the peripheral region shown in
FIG. 38
b
, MOS transistors are arranged in lower integrity than that of the memory cell region shown in
FIG. 38
a.
Hereinafter, steps of manufacturing such as the nonvolatile memory device will be shown schematically with reference to
FIG. 39
to FIG.
42
. Each of
FIG. 39
a
to
FIG. 42
a
shows a cross sectional view similar to an A-Aa cross sectional view shown in
FIG. 38
a
. Each of
FIG. 39
b
to
FIG. 42
b
shows a cross sectional view similar to a B-Ba cross sectional view shown in
FIG. 38
a
. Each of
FIG. 39
c
to
FIG. 42
c
shows a cross sectional view similar to a C-Ca cross sectional view shown in
FIG. 38
b
. Also, same reference numbers will be commonly fed to same portions over
FIG. 39
to FIG.
42
.
As shown in
FIG. 39
, a gate insulation film
102
is formed on a semiconductor substrate
101
. A poly crystalline silicon layer
103
formed on the gate insulation film
102
and a poly crystalline silicon layer
107
formed thereon are used as a floating gate in the memory cell region (See
FIGS. 39
a
and
39
b
) and are used as a part of the gate electrode in the peripheral region (See
FIG. 39
c
).
A reference number
108
in
FIGS. 39
a
and
39
b
shows a second gate insulating film which is, for instance, comprised of an ONO (Oxide-Nitride-Oxide) layer. A poly crystalline silicon layer
109
and a WSi (Tungsten Silicide) layer
110
are formed on the second gate insulating film. The poly crystalline silicon layer
109
is used as the gate connection line
163
. Silicon oxide layers
111
and
112
are formed on the WSi layer
110
. The WSi layer
110
is also used as a part of the control gate electrode in the memory cell region.
As shown in
FIG. 39
c
, the WSi layer
110
is used as a part of the gate electrode in the peripheral region. It should be noted that, as shown in
FIG. 39
, a silicon oxide layer
112
is formed above upper surfaces of the gate electrode in the memory cell region and the peripheral region, and on side surfaces of the gate electrode in the memory cell region and the peripheral region at this stage.
As shown in
FIG. 40
, a silicon nitride layer
113
with 40 nm in thickness is formed on the silicon oxide layer
112
by using a low pressure CVD (Chemical Vapor Deposition) method. A BPSG (Boron phosphor Silicate Glass) layer
114
with 400 nm in thickness is formed on the silicon nitride layer
113
in order to fulfill intervals between the gate electrodes by using a normal pressure CVD method. After that, the BPSG layer
114
is reflowed by adding heat with 850 degrees centigrade and nitrogen atmosphere. Moreover, a BPSG layer
115
with 300 nm in thickness is formed on the BPSG layer
114
. After that, the BPSG layer
115
is reflowed by adding heat with 850 degrees centigrade and nitrogen atmosphere. Simultaneously, dopants in the diffusion layer
129
are diffused.
As shown in
FIG. 41
, by using a CMP (Chemical Mechanical Polishing) method, parts of the BPSG layer
114
and
115
are removed so as to expose upper surfaces of the silicon nitride layer
113
. A silicon oxide layer
116
with 100 nm in thickness is formed by using a plasma CVD method. And then, a photo resist layer (not shown) is formed on the silicon oxide layer
116
and is processed into a desirable pattern by using a photolithography technique. Parts of the silicon oxide layer
116
, the BPSG layer
114
, and
115
are removed by using the patterned resist layer as a mask and RIE (Reactive Ion Etching) method, thereby forming a first contact hole
117
a.
The patterned photo resist layer is removed. And then, by using RIE (Reactive Ion Etching) method and the patterned silicon oxide layer
116
as a mask, the silicon nitride layer
113
and the gate insulating layer
102
that are located under a bottom surface of the contact hole
117
a
are removed so as to expose an upper surface of the semiconductor substrate
101
. Formations that are formed on a side surface of the contact hole
117
a
at the RIE method are removed. After that, by using a CVD method, a tungsten layer
117
with 400 nm in thickness is formed so as to cover the silicon oxide layer
116
and fulfill the contact hole
117
a.
As shown in
FIG. 42
, by using a CMP method, parts of the tungsten layer
117
and the silicon oxide layer
116
are removed so as to expose upper surfaces of the silicon nitride layer
113
in order to flatten and identify heights of an upper surface of the tungsten layer
117
and the silicon nitride layer
113
. A silicon oxide layer
118
with 450 nm in thickness is formed on the silicon nitride layer
113
and the tungsten layer
117
by using a plasma CVD method. A photo resist layer (not shown) is then formed on the silicon oxide layer
118
and patterned

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