Product including a silicon-containing functional layer and...

Semiconductor device manufacturing: process – Formation of semiconductive active region on any substrate – On insulating substrate or layer

Reexamination Certificate

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C438S474000, C438S766000

Reexamination Certificate

active

06410407

ABSTRACT:

BACKGROUND OF THE INVENTION
Field of the Invention
The invention relates to a product including a silicon-containing functional layer and an insulating layer made of silicon dioxide. The invention additionally relates to a method for fabricating such a product.
A product of the type mentioned above is known in the field of semiconductor technology, by the term “Silicon On Insulator Substrate” (“SOI substrate” hereinafter) and has the above-mentioned structure. As a rule, such a structure is built on a base layer which is likewise composed of silicon.
Such a product is described in a paper by Irita et al. in the Japanese Journal of Applied Physics 20 (1981) L909. A method for fabricating such a product is also described. The product may include a plurality of configurations made of a functional layer and an insulating layer stacked on top of one another.
According to U.S. Pat. No. 5,468,657, nitrogen is implanted into the insulating layer of a product of the type mentioned above, and subsequently a thermal treatment is carried out. In the course of this, the nitrogen migrates into a transition zone between the functional layer and the insulating layer, where it serves to saturate broken chemical bonds. Such broken chemical bonds may have been formed during the fabrication of the product, with the implantation of oxygen into silicon. Consequently, certain regions of the product are doped with nitrogen in order to passivate these regions.
In the context of the technology of electronic semiconductor components, a product of the type mentioned above can be advantageously used as a basis for an electronic semiconductor component. In this case, the semiconductor component is formed from correspondingly doped zones in the functional layer, and the insulating layer is beneficially employed for delimiting and insulating the component.
One problem that can arise in the case of a semiconductor component in a product of the type mentioned above, is the migration or segregation of dopants from the functional layer into the insulating layer by diffusion. This diffusion is particularly pronounced if the product is exposed to a heat treatment at an elevated temperature in order to fabricate the semiconductor component. In conventional practice, such a loss of dopants has to be determined by a corresponding analysis of the fabrication process and must be compensated for by a correspondingly excessive doping of the functional layer.
A substrate composed solely of silicon, without the insulating layer made of silicon dioxide, does not exhibit the segregation of the dopant material outlined above. Therefore, it is not possible to transfer or use a doping specification, which is applicable to a pure silicon substrate, to a substrate with a functional layer made of silicon on an insulating layer made of silicon dioxide of a conventional type.
SUMMARY OF THE INVENTION
It is accordingly an object of the invention to provide a product having a silicon-containing functional layer and an insulating layer made of silicon dioxide and a corresponding method of fabricating such a product which overcome the above-mentioned disadvantages of the heretofore-known products and fabrication methods of this general type and which prevent the dopant segregation described above.
With the foregoing and other objects in view there is provided, in accordance with the invention, a product, including:
a functional layer containing silicon;
an insulating layer formed of silicon dioxide; and
a stop layer disposed between the functional layer and the insulating layer and connecting the functional layer to the insulating layer, the stop layer being formed of silicon nitride and having a thickness of between 2 nm and 4 nm.
In other words, the product according to the invention includes a silicon-containing functional layer and an insulating layer made of silicon dioxide and further includes, as a distinguishing feature, a stop layer made of silicon nitride. The stop layer is provided between the functional layer and the insulating layer and connects or bonds the functional layer to the insulating layer.
In the case of this product, a special stop layer is provided between the functional layer and the insulating layer. The stop layer is formed from a material in which a conventional dopant material cannot diffuse to a significant extent.
Consequently, this stop layer acts as a diffusion barrier between the functional layer and the insulating layer and accordingly prevents the segregation of a dopant from the functional layer. As a result, the stability of a doped zone in the functional layer is ensured. The stability is due to the correspondingly favorable properties of the silicon nitride itself at an elevated temperature, as may occur during a heat-treatment process that is occasionally necessary in accordance with conventional practice. As a result, the invention also makes it possible to transfer a doping specification which is applicable to a substrate composed solely of the material of the functional layer to the corresponding product according to the invention.
It is assumed that the segregation effect that is to be prevented in accordance with the invention is primarily caused by the high diffusion tendency of every customary dopant in silicon dioxide. Therefore, details of the composition of the functional layer are not a matter of absolute importance.
Despite that, in accordance with another feature of the invention, the functional layer is essentially composed of silicon.
As defined above, the stop layer has preferably a thickness of between 2 nm and 4 nm. The stop layer is thus thin enough not to have a significant influence on the relevant mechanical properties of the product and, in particular, is thin enough not to cause any undesirable mechanical stresses in the product.
The functional layer of the product is furthermore preferably essentially monocrystalline and thus allows the use of the product in the context of the conventional technology of semiconductors.
In accordance with a further feature of the invention, the functional layer is configured to be formed with doped zones.
With the objects of the invention in view there is also provided, a method for fabricating a product including a silicon-containing functional layer, an insulating layer made of silicon dioxide, and a stop layer made of silicon nitride, the stop layer being disposed between the functional layer and the insulating layer and connecting the functional layer to the insulating layer. The method includes the steps of:
providing a blank part including a functional layer and an insulating layer, the functional layer being disposed directly on the insulating layer and being bonded to the insulating layer;
implanting nitrogen with a given dose into the insulating layer; and
heat treating the blank part after the implanting step for causing a diffusion of the nitrogen to the functional layer and a bonding of the nitrogen to silicon of the functional layer for forming a stop layer with a thickness of between 2 nm and 4 nm, the thickness of the stop layer being a function of the given dose.
Consequently, the method starts out with a blank part, of the type of a conventional SOI substrate, in which the functional layer is connected or bonded directly to the insulating layer. The term blank or blank part in this context means that the part, such as the SOI substrate, is not yet in its finished state and still has to be processed. The stop layer is produced subsequently between the functional layer and the insulating layer by nitrogen being implanted into the functional layer, the nitrogen being brought by diffusion to the functional layer and being bonded to silicon of the functional layer in order to form the stop layer. The stop layer is produced automatically, as it were, with only a small thickness, since the bonding of the silicon to the nitrogen with the formation of the desired silicon nitride takes place in the context of a chemical process which is self-regulating. This chemical process is also not particularly dependent on the temperature se

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