Metal nanoparticle having a self-assembled monolayer on its...

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

Reexamination Certificate

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C977S777000, C977S778000, C977S779000

Reexamination Certificate

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07923110

ABSTRACT:
A metal nanoparticle which is prepared by forming a self-assembled monolayer including a terminal reactive group on the surface thereof, and introducing a functional group capable of being removed by the action of an acid or an base into the terminal reactive group wherein the self-assembled monolayer is built up of a thiol, an isocyanide, an amine, a carboxylate or a phosphate compound having the terminal reactive group, or built up of a thiol, an isocyanide, an amine, a carboxylate or a phosphate compound having no terminal reactive group followed by introducing the terminal reactive group thereto; and a method for forming a conductive pattern using the same are provided. Since the metal nanoparticle of exemplary embodiments of the present invention can easily form a high conductive film or a high conductive pattern through photo-irradiation and photo-degradation and randomly regulate its conductivity when occasions demand, it can be advantageously applied to an antistatic washable sticky film, antistatic shoes, a conductive polyurethane printer roller, an electromagnetic interference shielding, and the like.

REFERENCES:
patent: 7166412 (2007-01-01), Park et al.
patent: 7473513 (2009-01-01), Park et al.
Yu Tai Tao, “Structure Comparison of Self-Assembled Monolayers of n-Alkanoic Acids on the Surfaces of Silver,Copper, and Aluminum” J. Am. Chem. Soc. 1993, 115, 4350-4358.
Paul E. Laibinis et al.“Comparison of the Structures and Wetting Properties of Self-Assembled Monolayers of n-Alkanethiols on the Coinage Metal Surfaces, Cu, Ag, Au1” J. Am. Chem. Soc. 1991, 113, 7152-7169.
A. N. Goldstein et al., “Melting in Semiconductor Nanocrystals” A. N. Goldstein, C. M. Echer, A. P. Alivisatos vol. 256 Jun. 5, 1992 pp. 1425-1427.
G. Schön et al.“A fascinating new filed in colloid science: small ligand-stabilized metal clusters and possible application in microelectronices” Colloid Polym Sci (1995) 275: 101-117.

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