Semiconductor device and manufacturing method therefor

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S669000, C438S687000, C438S688000, C438S945000, C438S947000, C438S952000, C438S975000

Reexamination Certificate

active

06197679

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to semiconductor devices, and more specifically, to a semiconductor device having a connecting hole not larger than 0.4 &mgr;m□ in size and an overlay mark. The present invention also relates to a method of manufacturing such a semiconductor device.
2. Description of the Background Art
In the manufacture of a semiconductor device, the higher integration and accompanying scaling down of the semiconductor device are making the width of a pattern line as well as the space between pattern lines smaller. In addition, strict overlay-accuracy for high density integration is required due to complication of the longitudinal structure of a device.
FIG. 11
is an illustration showing a conventional overlay technique. Overlapping is accomplished when a pattern on a photomask
20
is transferred to a wafer
21
. More specifically, in the overlaying, the position of a wafer overlay mark
23
in diffraction grating form formed on the wafer is measured using alignment light
24
through photomask
20
. The displacement between the position thus measured and a stage is corrected by moving the stage, and a chip pattern
25
on photomask
20
is transferred onto wafer
21
as a chip pattern
26
a
. It is noted that the wafer alignment pattern to be used for overlapping the next layer is also transferred at the same time.
There are at least two types of such overlay marks
22
, one for the alignment in the X direction and the other in the Y direction.
For the high density integration and accompanying scaling down of a semiconductor device, a technique for forming a fine pattern using a halftone phase shift mask (hereinafter referred to as a halftone mask) as photomask
20
has been proposed.
With reference to
FIG. 12
, photomasks in general includes a usual mask and a phase shift mask. A halftone mask is known as an example of the phase shift mask. The usual mask is a glass plate on which a pattern formed of metal such as Cr or MoSi is formed. The halftone mask is a glass plate on which a metal pattern of MoSiON, CrON or the like is formed.
The halftone mask is provided with a material which inverts the phase of light passing through non-shading portions in the location corresponding to shading portions formed on the usual mask. The halftone mask enhances the light contrast of the pattern and forms a fine pattern as compared with the usual mask.
FIGS. 13A and 13B
show the differences between the usual mask and the halftone mask. As for the halftone mask, the phase of light is inverted in the non-shading portion. The use of the halftone mask allows a pattern
26
and a peak
27
of light intensity to be clearly distinguished, thereby increasing resolution. A peak
28
of light intensity is however formed that can cause a ghost pattern as will be later described.
The problem associated with the manufacture of a semiconductor device by means of lithography technique using a conventional halftone mask will now be described.
With reference to
FIG. 14
, a connecting hole portion
29
and an overlay mark portion
30
are formed on a semiconductor substrate
9
. A first oxide film
10
, a barrier metal
11
, an aluminum film
12
, a titanium nitride film
13
and a second oxide film
14
are formed on semiconductor substrate
9
in connecting hole portion
29
. First and second oxide films
10
and
14
are formed on semiconductor substrate
9
in overlay mark portion
30
. Resist
15
for forming a connecting hole is provided in connecting hole portion
29
. Resist
15
b
for forming an overlay mark is provided in overlay mark portion
30
. A halftone mask
31
having non-shading portions in the positions to have a connecting hole and an overlay mark, respectively, is prepared. Halftone mask
31
has shading and non-shading portions
32
and
33
in overlay mark portion
30
. Resist
15
is irradiated with light
34
using halftone mask
31
. At this time, portions
35
and
36
to have a connecting hole and an overlay mark, respectively, are also exposed to the light. Further, a ghost pattern
37
is produced in the non-shading portion at the time. Ghost pattern
37
is formed by the phase-inverted light (corresponding to peak
28
in the light intensity) reflected by the surface of substrate
9
and directed upon resist
15
b.
The formation of ghost pattern
37
will now be described in further detail.
FIG. 22
shows changes in the reflectivity of the surface of an oxide film relative to changes in thickness when the oxide film is provided on a highly reflective substrate such as a silicon substrate. As is apparent from
FIG. 22
, the amplitude of the reflectivity caused by the change in the thickness of the oxide film is large. The change in the diameter of the opening portion of resist is accordingly large as shown in FIG.
23
. The amplitude period of reflectivity corresponds to about 1240 Å for a wavelength of 365 nm, and therefore the maximum and minimum values of reflectivity are within the range of the amplitude if the thickness of the oxide film changes by 620 Å. Thus, the diameter of the opening portion of the resist largely changes. When an oxide film having a thickness around 10000 Å is provided, the resist is inevitably exposed to light reflected from the silicon substrate due to the above mentioned change in the diameter if the thickness of the oxide film has a variation of 10% in its surface.
FIG. 24
is a graph showing the optimum exposure amount relative to the size of a connecting hole to be formed on the highly reflective substrate. The exposure amount allowing formation of a ghost pattern is also shown in FIG.
24
. Herein, the abscissa represents the size of the connecting hole, and the optimum exposure amount given in
FIG. 24
also applies to an overlay mark having a diameter of at least 1 &mgr;m, which can be regarded as the same in terms of size to the connecting hole having a diameter of 1 &mgr;m.
Assuming that the optimum exposure amount in the case of a connecting hole of 1 &mgr;m□ is normalized as 1, 1.5 times of the optimum exposure amount is required for a connecting hole of 0.4 &mgr;m□. Then, the optimum exposure amount allowing formation of a ghost pattern is sufficiently between the normalized 1.5 and 1. With reference to
FIG. 14
, ghost pattern
37
is consequently formed in the overlay mark portion in forming connecting hole
35
.
It is noted that the overlay mark can be well or poorly formed because of the variation in reflectivity as is apparent from
FIGS. 22 and 23
. This variation is the problem.
Returning to
FIGS. 14
,
15
and
16
, development of resist
15
to form resist patterns
15
a
and
15
b
actually results in resist patterns
15
a
and
15
b
having an undesired void portion
38
caused by the light for forming a ghost pattern peculiar to a halftone mask as shown in
FIG. 16
rather than those free from a void in a resist as shown in FIG.
15
.
It is noted that the overlay mark is in a striped pattern having a width of 1 &mgr;m and the size of the connecting hole is 0.4 &mgr;m□.
With reference to
FIGS. 16 and 17
, etching oxide film
14
using resist patterns
15
a
and
15
b
as masks forms oxide films
16
a
and
16
b
having a connecting hole
39
and a pattern
40
of an oxide film to be an overlay mark, respectively. A poorly shaped resist pattern causes a void
141
to be formed in pattern
40
of the oxide film, that is, in the overlay mark.
With reference to
FIG. 18
, a second interconnection layer
41
is formed to contact with a titanium nitride film
13
though connecting hole
39
. At the time, the component of the second interconnection layer is formed also in overlay mark portion
30
. Resist
42
is applied to cover second interconnection
41
.
Then, resist
42
is selectively exposed to light through a halftone mask using an overlay mark
40
as a reference for alignment to form a resist pattern
43
. Although resist pattern
43
is a portion for patterning second interconnection layer
41
, it i

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