Polymeric blends prepared with reactive initiators

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525131, 525529, 525530, 525930, C08F28304

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active

052410200

ABSTRACT:
Novel blends of polymers are produced by polymerizing interreactive compounds that form polymers in a non-free radical polymerization, and at least one monomer possessing carbon-to-carbon double bonds capable of polymerization by means of a free radical mechanism, in the presence of reactive initiators. In a preferred mode, a reaction mixture is formed comprising the interactive compounds, the monomers, and the reactive initiators. The interactive compounds are reacted in a initial step to form a first polymer connected to the reactive initiator. In a subsequent reaction, free radicals derived from the reactive initiator promote polymerization of the monomers to form a second polymer. The first polymer forms the continuous phase of the blend, while the second polymer comprises the discontinuous phase. As a consequence of the enhanced inter-phase adhesion resulting from the interaction of the reactive initiators with both polymers, the blends display superior tensile strengths, elastic recovery, and increased elongation at break.

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