Laser assisted cryoetching

Etching a substrate: processes – Gas phase etching of substrate – Application of energy to the gaseous etchant or to the...

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216 74, 438708, B44C 122, H01L 21302

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active

057414319

ABSTRACT:
Effective etching of several materials, including gallium nitride and gallium arsenide, without post etch surface damage has been achieved by using a mix of equal proportions of chlorine and methane. A sample is first cooled to a temperature of around 140.degree. K and is then irradiated by a series of pulses from a UV laser (for example a 193 nm ArF excimer laser). Using fluences of about 400 mJ/cm.sup.2 per pulse at repetition rates of about 10 pulses/second, an etch rate for gallium nitride of about 0.7 Angstroms per pulse was achieved. Typical pressure for the chlorine methane mix was about 2 mtorr. To achieve selective etching a number of approaches are possible including contact masking, projection printing, raster scanning, and moveable shadow masking with collimated laser light.

REFERENCES:
patent: 5112645 (1992-05-01), Sekine et al.
"Patterned, Photon-Driven, Cryoetching of GaAs and AlGaAs" by MC Shih et al, J. Vac. Sci Technology, vol. 13, 1995, pp. 43-54.
"Surface Chemical Reactions Studied by Laser Spectroscopy"; Kawasaki; 1990; Reza Kenkyu, 18(4), pp. 194-202; ISSN: 0387-0200.

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