Binderless zeolite catalysts, production thereof and catalytic r

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component

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502 67, B01J 2928

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active

050988948

ABSTRACT:
The binderless zeolite of this invention is comprised more than 90% of crystalline aluminosilicate which is produced by crystalized a binder contained in extrudate obtained by molding a mixture of crystalline aluminosilicate and binder of silica-alumina. This binderless zeolite can improve it's catalytic activity without weaken the strength of the extrudate, since a so-called secondary pores also act as catalyst. Especially, when more than 50% of TSZ zeolite is contained, the catalytic ability of binderless zeolite is so excellent that it is preferably used as the catalyst for selective cracking of n-parafins of alkylation of aromatics using alkylation agents such as alcohols and olefins. Excellent binderless zeolite can be obtained by subjecting extrudate, formed by molding a mixture of about from 30 to 70% by weight of at least one member selected from crystalline aluminosilicate, silica alumina xerogel or hydrothermally treated silica alumina xerogel, and from 70 to 30% by weight of silica alumina gel containing from 2 to 10% by weight of alumina, under hydrothermal conditions.

REFERENCES:
patent: 4757041 (1988-07-01), Oleck et al.
patent: 4847224 (1989-07-01), Fajula et al.
patent: 4975401 (1990-12-01), Kaeding et al.

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