Resist composition

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430281, 430910, G03C 176

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active

053606965

ABSTRACT:
This invention provides a process for producing a resist composition in which the content of relatively large undissolved particles is low just after production of the composition and the content of relatively large undissolved particles increases only to a small extent even if the composition is stored for a long period of time. Thus, this invention provides a process for producing a resist composition which comprises filtering a mixture of an alkali-soluble resin, a radiation-sensitive compound and a solvent by the use of a filter of which pore diameter is 0.1 .mu.m or below and of which particle-removing performance is 99% or above. Further, this invention provides also a resist composition comprising an alkali-soluble resin, a radiation-sensitive compound and an organic solvent not simultaneously having both acetoxy group and alkoxy group in its molecule, said composition containing undissolved particles having a particle diameter of 0.25 .mu.m or above in a number of 100 particles/ml or below, said undissolved particles being constituted of two particle groups one of which (the first group) has a particle diameter of 0.25-0.3 .mu.m and the other of which (the second group) has a particle diameter larger than 0.3 .mu.m, and the content of said first particle group having a particle diameter of 0.25-0.3 .mu.m being 50 particles/ml or below.

REFERENCES:
patent: 4281057 (1981-07-01), Castellani
patent: 5240517 (1993-08-01), Stout et al.
patent: 5258461 (1993-01-01), Facci et al.
Ultra Clean Technology, vol. 3, No. 2, pp. 83-89 (1991).
"Rejisuto Zairyou Purosesu Gijutsu" (Resist Materials. Process Technology) Gijutsu Joho Kyokai (The Japanese Soc. of Tech. Info), pp. 229-232 (1991).
"Sumitomo Kagaku" 1991-II, pp. 4-10 (1991).
IBM Technical Disclosure Bulletin, "Purification of Photoresist", vol. 11, No. 11, Apr. 69, N.Y., p. 1527.
"Photoresist Particle Control for VSLI Microlithography", M. L. Long, Solid State Technology, vol. 27, No. 3, Mar. '84, N.Y., pp. 159-160.
Photographic Abstracts, vol. 55, No. 3, 1975, London, GB, p. 83.
Japan Abstracts of Japan, vol. 7, No. 3 (C-143), Jan. 7, 1983.

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