HgCdTe epitaxially grown on crystalline support

Metal treatment – Compositions – Heat treating

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29576E, 148174, 148175, 148186, 427 76, 428620, H01L 2138, H01L 2136

Patent

active

046558489

ABSTRACT:
A layer of HgCdTe (15) epitaxially grown onto a crystalline support (10), e.g., of sapphire of GaAs. A CdTe substrate (5) is epitaxially grown to a thickness of between 1 micron and 5 microns on the support (10). A HgTe source (3) is spaced from the CdTe substrate (5) a distance of between 0.1 mm and 10 mm. The substrate (5) and source (3) are heated together in a thermally insulating, reusable ampoule (17) within a growth temperature range of between 500.degree. C. and 625.degree. C. for a growth step having a duration of between 5 minutes and 4 hours. Then an interdiffusion step is performed, in which the source (3) and substrate (5) are cooled within a temperature range of between 400.degree. C. and 500.degree. C. for a time of between 1 hour and 16 hours. In a first growth step embodiment, the source (3) and substrate (5) are isothermal. In a second growth step embodiment, the source (3) and substrate (5) are non-isothermal. Means are disclosed for preventing contamination of the reactants during HgTe (3) synthesis, and for polishing the HgCdTe layer (15).

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Marfaing et al., Crystal Growth, "A New Process of Crystal Growth: Evaporation-Diffusion Under Isothermal Conditions", Pergamon Press, N.Y., Jun. 20-24, 1966, pp. 549-552.
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