Wide range kinetic determination of peracid and/or peroxide...

Chemistry: analytical and immunological testing – Optical result

Reexamination Certificate

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C436S139000, C436S135000, C436S165000, C436S166000, C436S171000, C422S068100, C422S082050, C422S082090, C374S142000, C374SE13001, C356S246000

Reexamination Certificate

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08076155

ABSTRACT:
A use composition monitor determines the concentration of peracid and/or peroxide in a use composition using a kinetic assay procedure. A sample mixture containing a sample of the use composition, a diluent and at least one reagent is prepared and analyzed using, for example, an optical detector. Response data obtained by the detector is indicative of the optical absorbance of the sample mixture as a function of time. A processor analyzes the response data to determine a corresponding best fit linear relationship. Depending upon an expected concentration range, the initial absorbance and/or the slope of the best fit equation are used to calculate the concentrations of the peracid and peroxide in the use composition.

REFERENCES:
patent: 2007/0064228 (2007-03-01), Tartakovsky et al.
patent: 2006043855 (2006-04-01), None
Pettas et al, “Simultaneous spectra-kinetic determination of peracetic acid and hydrogen peroxide in a brewery cleaning-in-place disinfection process”, Analytical Chimica Acta, 522, 2004, pp. 275-280.
Harms et al, “Rapid and selective determination of peroxyacetic acid in disinfectants using flow injection analysis”, Analytica Chimica Acta, 389, 1999, pp. 233-238.
Davies et al, “Determination of Peracids in the Presence of a large excess of hydrogn peroxide using a rapid and convenient spectrophotometric method”, Analyst, 1988, 113, 1477-1479.
English-language abstract for WO2006043855 (Grinevich et al.).

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