Volatile liquid precursors for the chemical vapor deposition of

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156654, 156655, 156656, 156666, 427250, 427252, 427253, 4272551, C23C 1614, B44C 122, C03C 1500

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050857312

ABSTRACT:
Volatile liquid organometallic copper complexes are provided which are capable of selectively depositing a copper film onto metallic or other electrically conducting portions of a substrate surface under CVD conditions. These organometallic copper complexes are represented by the structural formula: ##STR1## wherein R.sup.1 and R.sup.3 are each independently C.sub.1 -C.sub.8 perfluoroalkyl, R.sup.2 is H, F or C.sub.1 -C.sub.8 perfluoroalkyl, R.sup.4 is H, C.sub.1 -C.sub.8 alkyl, or Si(R.sup.6).sub.3, each R.sup.5 is independently H or C.sub.1 --C.sub.8 alkyl and each R.sup.6 is independently phenyl or C.sub.1 -C.sub.8 alkyl. A process for depositing copper films using these organometallic copper complexes is also provided.

REFERENCES:
patent: 2704727 (1955-03-01), Pawlyk
patent: 2704728 (1955-03-01), Pawlyk
patent: 4842891 (1989-06-01), Miyazaki et al.
patent: 4948623 (1990-08-01), Beach et al.

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