Vapor phase chlorination of 1,1-dichloroethane

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 1700

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041928237

ABSTRACT:
In the preparation of methylchloroform by vapor phase chlorination of 1,1-dichloroethane, the formation of undesirable chlorohydrocarbon reaction products is suppressed by conducting the vapor phase reaction in the presence of a controlled amount of carbon dioxide gas.

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patent: 3138643 (1964-06-01), Taylor et al.
patent: 3304337 (1967-02-01), Jordan et al.
patent: 3983181 (1976-09-01), Strim et al.
patent: 4046823 (1977-09-01), Gordon et al.

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