Unsaturated polyesters

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Post imaging process – finishing – or perfecting composition...

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528272, 528279, 528283, 528296, 528297, 528298, 528299, 528300, 528301, 528302, 528306, 528307, 528308, 5283086, 430109, 430120, 430137, G03G 900

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054077729

ABSTRACT:
Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer. In a process for preparing the inventive polymer, the first, second, third monomer (and optionally a fourth monomer) and/or a catalyst undergo transesterification to form the unsaturated, linear polymer.

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patent: 5145762 (1992-09-01), Grushkin
patent: 5227460 (1993-07-01), Mahabadi et al.

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