Unsaturated hydrocarbon separation and recovery process

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By plural serial diverse separations

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585809, 585833, 585842, 585850, 585855, 585856, C07C 700, C07C 710, C07C 7152

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active

057446857

ABSTRACT:
A process is disclosed for the separation and recovery of an unsaturated hydrocarbon from its mixture with at least one other material by the selective and reversible complexation of the unsaturated hydrocarbon using a single cubane-type cluster of palladium, molybdenum and sulfur as a complexation agent.

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Murata et al., J. Am. Chem. Soc., vol. 116, pp. 3389-3398, 1994.
DuBois et al., J. Am. Chem. Soc., vol. 101, pp. 5245-5252 (1979).
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DuBois et al., Inorg. Chem., vol. 20, pp. 3064-3071 (1981).
McKenna et al., J. Am. Chem. Soc., vol. 105, pp. 5329-5337 (1983).
Birnbaum et al., Organometallics, vol. 10, pp. 1779-1786 (1991).

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