Total isomerization process with enhanced heat integration

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization

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Details

585738, 585739, 585750, 585820, 585826, C07C 513, C07C 712

Patent

active

060084278

ABSTRACT:
A method providing enhanced heat integration in isomerization processes having an isomerization reactor operating at a temperature less than about 232.degree. C. (450.degree. F.) and an adsorption zone operating at a temperature greater than about 260.degree. C. (500.degree. F.) has been developed. The method begins with flowing a fresh feed stream containing normal and non-normal hydrocarbons to either the isomerization reactor or the adsorption zone. A variable mass flow desorption effluent containing at least normal hydrocarbons is flowed to the isomerization reactor to form a reactor effluent containing normal hydrocarbons and isomerized non-normal hydrocarbons. The reactor effluent is cooled and separated into an adsorber feed stream and a hydrogen purge gas which are each conducted to an adsorption zone. In the adsorption zone, the normal hydrocarbons are adsorbed and the non-normal hydrocarbons are withdrawn and collected. The normal hydrocarbons are then desorbed from the adsorption zone using the hydrogen purge gas to produce the desorption effluent. The adsorber feed stream, the hydrogen purge gas, or both, are heat exchanged with the desorption effluent so that the desorption effluent flowing into the reactor is at about the operating temperature of the reactor and the adsorber feed stream, the hydrogen purge gas, or both, are partially heated. The partially heated adsorber feed stream, hydrogen purge gas, or both, are further heated using a controlled variable heat providing stream such as a steam or hot oil stream so that the temperature of the adsorber feed stream and hydrogen purge gas flowing into the adsorption zone are closer to the operating temperature of the adsorption zone.

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patent: 4929799 (1990-05-01), Holcombe et al.
patent: 5036035 (1991-07-01), Baba et al.
patent: 5120898 (1992-06-01), Baba et al.

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