Titanium nitride metal interconnection system and method of...

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S303000, C257S377000

Reexamination Certificate

active

06528835

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATIONS
Not applicable.
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT
Not applicable.
BACKGROUND OF THE INVENTION
This invention is in the field of integrated circuits, and is more specifically directed to interconnection systems and materials used therein.
Over recent years, many important advances have been made in the manufacture of integrated circuits, particularly in reducing the chip area required for the implementation of circuit elements. These advances include reduction in the critical dimensions of active elements such as transistors and interconnections, and the use of multiple interconnection layers in each integrated circuit. These advances have greatly increased the number of transistors that may be implemented in a given area, and thus greatly increased the functionality and performance of conventional integrated circuits, as well as reducing the manufacturing cost for such functionality.
However, the implementation of multiple interconnection layers introduces significant complexity in the design, layout, and manufacture of the integrated circuits, particularly as the feature sizes of the interconnections have become smaller, even into the submicron range. For example, modem integrated circuits such as high-density dynamic random access memories (DRAMs) may have on the order of five levels of interconnections; the formation and patterning of these multiple levels, as well as the provision of contacts among these levels of interconnections and contacts from interconnection levels to active devices (including the bulk silicon), can therefore become quite complex. Furthermore, as interconnect feature sizes become very small, the conductivity of individual interconnections become a concern, and as such the selection of the appropriate material for individual interconnection layers can become a relatively complex decision. Additional complications in the implementation of such interconnection layers also result from processing considerations, particularly where the integrated circuit wafers must be subjected to high temperature processing at a point in the manufacturing flow after the deposition and patterning of one or more of the interconnection layers.
An example of a conventional DRAM device constructed according to complementary metal-oxide-semiconductor (CMOS) technology, and illustrating multiple interconnection layers, is illustrated in
FIGS. 1 and 2
.
FIG. 1
illustrates two portions of partially-fabricated integrated circuit
20
, namely array portion
20
a
and periphery portion
20
p
formed at a surface of p-type substrate
2
. Specifically, periphery portion
20
p
as shown in
FIG. 1
includes a p-channel transistor having source/drain regions
6
formed within n-well
4
, at locations defined by field oxide structures
5
and gate structure
8
; gate structure
8
is vertically separated from the channel region between source/drain regions
6
by a gate dielectric, in the conventional manner. Gate structures
8
may be encapsulated, as shown in
FIG. 1
, to permit contacts for subsequent interconnection layers to be made in a self-aligned manner relative to gate structures
8
, without shorting thereto. Of course, n-channel periphery transistors will also be implemented in periphery portion
20
p
, within a p-type well, but are not shown in
FIGS. 1 and 2
for the sake of clarity.
In this example, insulating material
10
collectively refers to multiple insulating layers, which may include a barrier layer, a doped oxide (BPSG) layer and additional insulating layers that overlie gate structure
10
. First-level metal conductor
22
makes contact to one of source/drain regions
6
, through a contact opening etched through overlying insulating material
10
at that location. Additional metallization layers, such as second-level metal
24
and third-level metal
26
are similarly formed in periphery portion
20
p
as shown in
FIG. 1
, physically and electrically insulated from one another by additional levels of insulating material
10
with vias therethrough for purposes of electrical connection.
Array portion
20
a
of integrated circuit
20
contains, in the portion illustrated in
FIG. 2
a
, two storage capacitors which are formed in a “crown” fashion, as described in further detail in commonly assigned copending application Ser. No. 08/845,755, filed Apr. 25, 1997, entitled “A Silicon Nitride Sidewall and Top Surface Layer Separating Conductors”, incorporated hereinabove by reference. In this example, the storage capacitors are formed by field plate
18
that is electrically coupled to a fixed voltage, and separated from individual second plates
16
by capacitor dielectric layer
17
. Each of plates
16
,
18
are preferably formed of polysilicon, while capacitor dielectric layer
17
may be formed of silicon dioxide, of silicon nitride, or of a sandwich structure of silicon dioxide and silicon nitride, as known in the DRAM art. Plates
16
are respectively connected to polysilicon plugs
12
and thus to n-type source drain regions
7
at the surface of p-type well
9
; the location of which are defined by field oxide structures
5
and gate structures
8
. Well
9
is formed within deep n-type well
3
, at a surface of p-type substrate
2
.
Bit line
15
also extends laterally above gate structures
8
and field oxide structures
5
, separated therefrom by one of the layers of insulating material
10
, while gate structures
8
for some distance along array portion
20
a
, perpendicularly relative to bit line
15
, to control connection of the storage capacitors to their respective bit lines, in the usual manner for DRAMs. As shown in
FIGS. 1 and 2
, bit line
15
makes contact to source/drain regions
7
both directly and indirectly. Within array portion
20
a
, between adjacent storage cells, bit line
15
extends into and through a bit line contact BLC (
FIG. 2
) to make contact to source/drain region
7
. Away from the storage cells, first level metallization layer
22
is also provided to strap bit line
15
to another source/ drain region
7
. Second-level metal layer
24
and third-level metal layer
26
are also provided in array portion
20
a
, to provide interconnection among the various circuit elements.
As is evident from
FIGS. 1 and 2
, bit line
15
is formed prior to the formation of capacitor plates
16
,
18
, and as such must have sufficient thermal stability to be able to withstand the temperature sequence used in the formation of plates
16
,
18
, as well as capacitor dielectric
17
therebetween. Accordingly, in this conventional arrangement of
FIGS. 1 and 2
, bit line
15
must be formed of a material that can withstand such processing. One particular example of such material is silicide-clad polysilicon, such as tungsten polycide. Alternatively, a multi-layer structure of n+ doped polysilicon (when contacting n-type source/drain regions as illustrated in
FIGS. 1 and 2
) stacked with tungsten disilicide may also be used. These materials differ quite radically from conventional aluminum metallization as used in metal layers
22
,
24
,
26
, as such metallization is not able to withstand processing temperatures above 450° C., and as such cannot withstand the processing required to form capacitor plates
16
,
18
and capacitor dielectric
17
.
However, these materials are not suitable for use as a first level metal interconnection layer in periphery portion
20
p
, or even within array portion
20
a
, due to the relatively high contact resistance provided by these materials, and also because these materials do not present a barrier to the diffusion of dopant (of either n-type or p-type) or of silicon therethrough. As a result, first level metal layer
22
is necessary in the conventional DRAM integrated circuit structure of
FIG. 1 and 2
to provide interconnection to elements in periphery portion
20
p
, and as a strap connection from bit line
15
to source/drain region
7
as shown.
As is evident from the conventional arrangement of
FIGS. 1 and 2
, the

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