Thermosetting acryloyloxy-terminate butadiene polymers

Details Thermosetting acryloyloxy-terminate butadiene polymers Thermosetting acryloyloxy-terminate butadiene polymers

1975-02-06

1977-07-05

Tillman, Murray

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

20415915, 20415916, 260879, 260880R, 260885, 361398, C08F 800, C08L 900, C08L 3102

Patent

active

040338401

ABSTRACT:
A thermosetting resin composition having improved properties as an electrical insulating material and being particularly suited for use in printed circuit boards, consists essentially of an acryloyloxyl- or methacryloyloxyl- terminated butadiene homopolymer or copolymer, for example, with acrylonitrile or styrene, an ethylenically unsaturated monomer capable of copolymerizing with the terminating acryloyloxyl or methacryloyloxyl groups of the butadiene homopolymer or copolymer, and an acid anhydride containing at least one ethylenically unsaturated group in its molecule. In preferred compositions of the invention, there are from 1.5 to 3.0 terminating acryloyloxyl or methacryloyloxyl groups per molecule of the butadiene homopolymer or copolymer, and the amounts of the ethylenically unsaturated monomer and of the acid anhydride are from 50 to 200 weight percent and from 5 to 20 weight percent, respectively, based on the weight of the terminated butadiene homopolymer or copolymer. A particularly desirable composition is obtained when the acryloyloxyl- or methacryloyloxyl-terminated polymer or copolymer is at least 70 weight percent 1,2-polybutadiene.

REFERENCES:
patent: 3455801 (1969-07-01), D'Alelio
patent: 3733370 (1973-05-01), Thompson et al.
patent: 3899611 (1975-08-01), Hall

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