Tetrathiocarbonate batch process

Chemistry of inorganic compounds – Carbon or compound thereof

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G01B 3126

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053975570

ABSTRACT:
Salts of tetrathiocarbonic acid are produced by a batch process in which a hydroxide, hydrogen sulfide, sulfur and carbon disulfide are reacted sequentially. The salts are produced as aqueous solutions having concentrations of upwards of 30 percent by weight.

REFERENCES:
patent: 4726144 (1988-02-01), Young et al.
"Mass Transfer Operations", by R. E. Treybal, 2nd edition 1968 (no month) pp. 413-414.
Journal of the Chemical Society, 1921, vol. 119, pp. 38-54, Yeoman: Trithiocarbonates and Perthiocarbonates. III. Trithiocarbonates and Perthiocarbonates (no month).
Journal of the Chemical Society, vol. 89 (II), 1906, pp. 1812-1818, (no month) O'Donoghue and Kahan: CLXXIV. Thiocarbonic Acid and Some of its Salts.
Journal of Chemical Society, vol. 128(II), 1928, pp. 2326-2332, Mills and Robinson: Ammonium Polysulphides. CCCVI-Ammonium Polysulphides, Hydrogen Pentasulphide, and the Thiocarbonic Acids (no month).
Topics in Sulfur Chemistry, vol. 2, "Carbon Sulfides and Their Inorganic and Complex Chemistry", by G. Gattow and W. Behrendt, Georg Thieme Publishers Stuttgart 1977, pp. 154-178 (no month).

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