Telomerization of olefins

Details Telomerization of olefins Telomerization of olefins

1986-06-30

1987-06-02

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

534587, 534885, 560 81, 560 96, 560105, 560202, 570206, C07C 67347, C07C10706, C07C 1722

Patent

active

046705791

ABSTRACT:
An olefin, especially an activated olefin, is telomerized by reaction with an arylamine, such as an aniline, in the presence of an alkyl nitrite, a copper catalyst, and a catalytic amount of water and/or acid and in the absence of more than about 0.5 volume part of inert solvent per volume part of olefin.

REFERENCES:
Doyle et al, J. Org. Chem., vol. 42, No. 14, pp. 2431-2436, (1977).
Kawamatsu et al, Arzneim.-Forsch,/Drug Res., vol. 30(I), No. 5, pp. 751-758, (1980).
Freidlina et al, Doklady Akadomii Nauk 555R, vol. 183, No. 5, pp. 1113-1116, (1968), (translation).
Rondestvedt I, Organic Reactions, vol. 11, pp. 189-260.
Rondestvedt II, Organic Reactions, vol. 24, pp. 225-259.

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