Synthesis of linear primary alcohols from internal olefins

Details Synthesis of linear primary alcohols from internal olefins Synthesis of linear primary alcohols from internal olefins

1975-06-20

1976-10-05

Evans, Joseph E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2606832, C07C 2916

Patent

active

039844862

ABSTRACT:
It has been discovered that heating C.sub.4 -C.sub.17 internal olefins to 300.degree.F to 500.degree.F for about 15 to 30 minutes in the presence of an oxo catalyst prior to hydroformylation results in a higher selectivity to primary alcohols than does the conventional hydroformylation procedure of heating all the reactants together.

REFERENCES:
patent: 3139460 (1964-06-01), Eisenmann
patent: 3239569 (1966-03-01), Slaugh et al.
patent: 3432570 (1969-03-01), Hoffman et al.
patent: 3542896 (1970-11-01), Butte
patent: 3907909 (1975-09-01), Macaluso et al.

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