Food or edible material: processes – compositions – and products – Products per se – or processes of preparing or treating... – Noncarbohydrate sweetener or composition containing same
Reexamination Certificate
1998-01-28
2001-01-30
Wong, Leslie (Department: 1761)
Food or edible material: processes, compositions, and products
Products per se, or processes of preparing or treating...
Noncarbohydrate sweetener or composition containing same
C426S804000
Reexamination Certificate
active
06180155
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to a sweetener having an improved sucrose-like taste and a process for the preparation and use of this sweetener.
DESCRIPTION OF THE PRIOR ART
Artificial sweeteners having a low nutritive value are increasingly being used instead of sugar to decrease the intake of calories for dietetic or medical reasons. As is known, they are distinguished by a very much greater sweetening power than the naturally occurring sugars. They are therefore very highly suitable for sweetening foods and beverages. It is a disadvantage that all artificial sweeteners when set in a relatively strong sweetness show some degree of a foreign taste. The taste quality of the sweetness also generally deviates from that of sucrose which has become the model for the evaluation of sweetness owing to long habituation.
To mask the foreign taste, a number of various non-sweet-tasting additives such as maltol, ethylmaltol, citric acid, tartaric acid or quinine sulfate have been previously added to the artificial sweeteners (DE-A 20 60 634). These compounds have principally been described to mask the foreign taste of saccharin. In addition, modified artificial sweeteners are disclosed by DE-C 25 60 544 and DE-A 25 56 109. Here, taste modifiers such as potassium aluminum sulfate or naringin are added to known artificial sweeteners such as aspartame and cyclamate in order to modify the aftertaste of the artificial sweeteners.
To improve the taste quality of artificial sweeteners, mixtures of artificial sweeteners are also used. DE-B 26 28 294 discloses artificial-sweetener mixtures having an improved sucrose-like taste. It is described herein that the quality of the artificial sweeteners and the similarity to sucrose of the artificial sweeteners may be improved by mixing with other artificial sweeteners. A reason for the use of mixtures of artificial sweeteners is that some of the known artificial sweeteners develop their sweetness on the tongue in a highly delayed manner or else produce a very rapid impression of sweetness which also subsides rapidly, however. This disadvantage may be substantially compensated for by adding artificial sweeteners having a sweetness which persists for a relatively long time or if appropriate by mixing with natural sugar. To improve the similarity to sucrose, in DE-B 26 28 294, an artificial-sweetener mixture of 3,4-dihydroxy-6-methyl-1,2,3-oxathiazin-4-one 2,2-dioxide (acesulfame) with another of the known artificial sweeteners such as aspartame, saccharin and cyclamate is proposed. In EP 3 19 984 B1, the similarity to sucrose of the taste of artificial-sweetener mixtures in improved still further by mixing at least one synthetic sweetener with dearomatized and concentrated fruit preparations of 60 to 80° Brix. By mixing artificial sweetener with sweet-tasting carbohydrates in this case an improvement in the taste of artificial-sweetener mixtures is achieved. JP 59/154956 discloses a sweetener of acesulfame-K and fructose. In addition, DE-A 33 31 517 discloses sweeteners which comprise mixtures of acesulfame-K with, inter alia, lactose or fructose. In this case too, by mixing artificial sweeteners with sweet-tasting carbohydrates, an improvement in the similarity to sucrose in the intended result.
Rhamnose is known as a starting product for the preparation of 2,5-dimethyl-4-hydroxy-3(2H)-furanone. This substance is an important impact component in many fruit aromas and in therefore frequently used in aroma compositions for the food industry. Furthermore it is known that rhamnose can be used as starting substance for reaction aromas. In addition to the formation of furaneol, the formation of 5-methylfurfural and other Maillard reaction products from rhamnose and nitrogen-containing compounds is also described in the literature (A. F. Pisarnitskii et al., Applied Biochemistry and Microbiology 28 (1), 97 to 100 (1992); R. Silwar, Zeitechrift f{umlaut over (u)}r Lebensmitteluntersuchung und -Forschung 195 (2), 112 to 119 (1992)).
Rhamnose has a considerably lower sweetening power than sucrose. Therefore this compound is not used for sweetening foods either.
In the literature, the term “full sweetness” is frequently described (by Rymon Lipinski and Schiwerk: Handbuch S{umlaut over (u)}fungsmittel [Sweetener Handbook], Behr's Verlag 1991; Nabors, L. O. and Gelardi R. W.: Alternative Sweeteners, Marcel Dekker Inc., 1991). This term in meant to express the fact that this is a harmonious and full-bodied sweetness. In contrast thereto, a “watery sweetness” is described as flat and without body and cannot be closely compared with that of sucrose.
The object of the present invention is to prepare a sweetener which has a harmonious and full-bodied sweetness which is comparable with that of sucrose and which in addition improves the taste quality of foods sweetened with it by intensifying the aroma development, and to specify a process for the preparation thereof and use thereof.
SUMMARY OF THE INVENTION
It has now surprisingly been discovered that deoxysugars, in particular rhamnose or fucose, in low dosage concentrations can improve the similarity to sucrose of intensive sweeteners.
Furthermore it is shown that, owing to the addition of deoxysugars such as rhamnose or fucose, foods sweetened with artificial sweeteners taste bettor. A more complete development of the aroma results. In addition to the improvement of the similarity to sucrose, owing to the addition of rhamnose, the flavor quality of foods sweetened with artificial sweetener also improves. This type of aroma enhancement by the addition of rhamnose without the addition of heat was not known hitherto.
The object posed is therefore achieved by a sweetener of the type mentioned at the outset which
a) contains at least one artificial sweetener or a mixture of different artificial sweeteners and
b) contains at least one deoxysugar.
The mixture components a) and b) are present in a ratio within 1:1000 to 1000:1, preferably within 10:1 to 1:10 parts by weight.
The component a) in the sweetener according to the invention is preferably acesulfame-K, aspartame, sodium cyclamate, saccharin, neohesperidin dihydrochalcone, trichlorogalactosucrose, alitane, thaumatin or stevioside. Either one or a plurality of these artificial sweeteners can be used for mixing with the component.
Preference is given to the use as component a) of acesulfame-K alone, a mixture of acesulfame-K and aspartame or a mixture of acesulfame and sodium cyclamate.
Component b) is preferably rhamnose or fucose.
DETAILED DESCRIPTION
There are various potential methods for the preparation of rhamnose. On the one hand, rhamnose can be isolated from constituents of plant materials such as rutin, naringin or hesperidin after cleavage of the glycosidic bonds. On the other hand, rhamnose can also be produced by biotechnology from plant raw materials (U.S. Pat. No. 4,933,281). Rhamnose is generally used as L-rhamnose monohydrate. This substance occurs in crystalline form.
To prepare the abovementioned sweetener, the individual artificial sweeteners or artificial-sweetener mixtures can then be mixed with rhamnose in pulverulent form. Alternatively, an aqueous artificial sweetener solution can also be prepared from the abovementioned artificial sweeteners and rhamnose. In addition, this solution can be spray-dried in order to obtain a corresponding sweetener powder having improved sucrose-like taste.
The sweetener thus prepared can be used, inter alia, to produce artificial sweeteners for table use.
The sweetener according to the present invention can further be used in the home or in industrial food production for sweetening foods, in particular for sweetening liquid foods such as soft drinks or dairy products or ice products both in solid form and as a solution. In addition, all other foods such as bakery products, desserts and delicatessen products can also be sweetened therewith.
The sweetener according to the present invention is used in foods usually in a concentration of 1 to 5000 mg/kg of ready-to-eat food. The mixture pa
Bohshar Manfred
Lotz Andreas
Connolly Bove & Lodge & Hutz LLP
Nufrinova GmbH
Wong Leslie
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