Supported heteropoly acid catalysts

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs

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4233291, 423299, 423304, 423305, 423306, 423277, 423326, 502 73, 502 62, 502 64, 502 65, 502 66, 502 71, 502202, 502204, 502206, 502207, 502208, 502209, 502210, 502211, 502213, 502214, B01J 2904, B01J 2906, B01J 27185, B01J 2102

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053669452

ABSTRACT:
There is provided a catalyst comprising a heteropoly acid, such as phosphotungstic acid, supported on a mesoporous crystalline material, such as M41S. A particular form of this M41S support is designated as MCM-41. There is also provided a method for preparing this catalyst by impregnating the heteropoly acid on the support. There is also provided a process for using this catalyst to catalyze acid catalyzed reactions, such as the isomerization of paraffins and the alkylation of aromatics.

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Ono, Y. et al., "The Catalytic Behavior of Metal Salts of Heteropolyacids in the Vapor-phase Synthesis of Methyl t-Butyl Ether," Tokyo Institute of Tech (1984).
Matsuda, T. et al., "Effect of Pretreatment on the Acidity of Heteropoly Compounds in Butene Isomerization," J. Chem. Soc., 77, 3107-3117 (1981).
Nowinskia, K. "Evidence for Superacid Sites on the Ammonium Salt of 12-Tungstophosphoric Acid from a Catalytic Test Reaction," J. Chem. Soc., 44 (1990).
Nowinska, K. et al., "Catalytic Activity of Supported Heteropoly Acids for Reactions requiring Strong Acid Centres," J. Chem. Soc., 87(5), 749-753 (1991).
Hattori, H. et al., "Solid Super Acids: Preparation and Their Catalytic Activities for Reaction of Alkanes," J. Catal., 68, 132-143 (1981).

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