Source reagent compositions for CVD formation of gate...

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

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C534S015000, C427S124000

Reexamination Certificate

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07005392

ABSTRACT:
A CVD Method of forming gate dielectric thin films on a substrate using metalloamide compounds of the formula M(NR1R2)x, wherein M is selected from the group consisting of: Zr, Hf, Y, La, Lanthanide series elements, Ta, Ti, Al; N is nitrogen; each of R1and R2is same or different and is independently selected from the group consisting of H, aryl, perfluoroaryl, C1–C8alkyl, C1–C8perfluoroalkyl, alkylsilyl and x is the oxidation state on metal M; and an aminosilane compound of the formula HxSi(NR1R2)4-x, wherein H is hydrogen; x is from 0 to 3; Si is silicon; N is nitrogen; each of R1and R2is same or different and is independently selected from the group consisting of H, aryl, perfluoroaryl, C1–C8alkyl, and C1–C8perfluoroalkyl. By comparison with the standard SiO2gate dielectric materials, these gate dielectric materials provide low levels of carbon and halide impurity.

REFERENCES:
patent: 4895709 (1990-01-01), Laine
patent: 5003092 (1991-03-01), Beachley, Jr.
patent: 5139825 (1992-08-01), Gordon et al.
patent: 5178911 (1993-01-01), Gordon et al.
patent: 5204314 (1993-04-01), Kirlin et al.
patent: 5225561 (1993-07-01), Kirlin et al.
patent: 5280012 (1994-01-01), Kirlin et al.
patent: 5417823 (1995-05-01), Narula et al.
patent: 5453494 (1995-09-01), Kirlin et al.
patent: 5536323 (1996-07-01), Kirlin et al.
patent: 5583205 (1996-12-01), Rees, Jr.
patent: 5726294 (1998-03-01), Rees, Jr.
patent: 5820664 (1998-10-01), Gardiner et al.
patent: 5820678 (1998-10-01), Hubert et al.
patent: 5876503 (1999-03-01), Roeder et al.
patent: 5919522 (1999-07-01), Baum et al.
patent: 5924012 (1999-07-01), Vaartstra
patent: 5972430 (1999-10-01), DiMeo, Jr.
patent: 5976991 (1999-11-01), Laxman et al.
patent: 6013553 (2000-01-01), Wallace et al.
patent: 6015917 (2000-01-01), Bhandari et al.
patent: 6020243 (2000-02-01), Wallace et al.
patent: 6060406 (2000-05-01), Alers et al.
patent: 6110529 (2000-08-01), Gardiner et al.
patent: 6159855 (2000-12-01), Vaartstra
patent: 6177135 (2001-01-01), Hintermaier et al.
patent: 6348412 (2002-02-01), Vaartstra
patent: 2002/0192952 (2002-12-01), Itoh et al.
patent: 2002/0197402 (2002-12-01), Chiang et al.
patent: 2001008502 (2001-02-01), None
patent: WO 00/67300 (2000-11-01), None
Bradley and Thomas, “Metallo-organic compounds containing metal-nitrogen bonds. Part I. Some dialkylamino-derivatives of titanium and zirconium” Journal of the Chemical Society, 1960, pp. 3857-3861.
Jones, et al., “MOCVD of Zirconia Thin Films by Direct Liquid Injection Using a New Class of Zirconium Precursor”, Chem. Vap. Dep., vol. 4, 1998, pp. 46-49.
D.C. Bradley, et al., “Metalorganic Compounds Containing Metal-Nitrogen Bonds: Part I, Some Dialkyamino Derivatives of Titanium and Zirconium”, J. Chem. Soc., 1960, 3857).
D.C. Bradley, et al., “Metalorganic Compounds Containing Metal-Nitrogen Bonds: Part III. Dialkylamino Compounds of Tantalum”, Candadian J. Chem., 40, 1355 (1962).
S. Giles, et al., “Deposition of (Ti,Al)N thin films by organometallic chemical vapor deposition: thermodynamic predictions and experimental results”, Elsevier Science, SA, Surface and Coatings Technology, 94-95 (1997), pp. 285-290.
Kozoh Sugiyama, et al., “Low Temperature Deposition of Metal Nitrides by Thermal Decomposition of Organometallic Compounds”, Journal of the Electrochemical Society, vol. 122, No. 11, Nov. 1975.
R. Juza, et al., “Ammonothermal Synthesis of Magnesium and Beryilium Amides”, Angew. Chem. Inte. Ed., 5, (2), 247 (1966).
U.S. Appl. No. 07/927,134, filed Aug. 7, 1992, Kirlin et al.
U.S. Appl. No. 07/615,303, filed Nov. 19, 1990, Brown.
U.S. Appl. No. 07/549,389, filed Jul. 6, 1990, Kirlin et al.

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