Single-crystal diamond of very high thermal conductivity

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With a step of measuring – testing – or sensing

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423446, 117929, C30B 2904

Patent

active

054192765

ABSTRACT:
Single-crystal diamond consisting of isotopically pure carbon-12 or carbon-13 has been found to have a thermal conductivity higher than that of any substance previously known, typically at least 40% higher than that of naturally occurring IIA diamond. It may be prepared by a method comprising comminution of diamond of high isotopic purity, such as that obtained by low pressure chemical vapor deposition employing an isotopically pure hydrocarbon in combination with hydrogen, followed by conversion of the comminuted diamond to single-crystal diamond under high pressure conditions.

REFERENCES:
patent: 3895313 (1975-07-01), Seitz
patent: 4034066 (1977-07-01), Strong et al.
patent: 4073380 (1978-02-01), Strong et al.
patent: 4434188 (1984-02-01), Kamo et al.
patent: 4544540 (1985-10-01), Tsuji
patent: 4617181 (1986-10-01), Yazu et al.
patent: 4816286 (1989-03-01), Hirose
Stromberg et al. "Sintering of Diamond at 1800.degree. C.-1900.degree. C. and 60-65 KBar", American Ceramic Bulletin, vol. 49, No. 12, (1970) pp. 1030-1032.
Clancy, The Cardinal of the Kremlin, (Barkley Books, Copyright Jul. 1988), pp. 112-113.
Davies, Diamond (Bristol England: Adam Hilger Ltd.), 1989, p. 138.
Seitz, "Isotopic Enhancement of Thermal Conductivity and Damage Thresholds in Diamond"Papers given Feb. 6, 1987, at Lincoln Laboratories.

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