Shallow trench isolation formation with two source/drain...

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Grooved and refilled with deposited dielectric material

Reexamination Certificate

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C438S424000, C438S433000

Reexamination Certificate

active

06380047

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a method of manufacturing a semiconductor device comprising trench isolation. The invention has particular applicability in manufacturing high density semiconductor devices with submicron design features and active regions isolated by shallow insulated trenches.
BACKGROUND ART
Current demands for high density and performance associated with ultra large scale integration require submicron features of about 0.25 microns and under, increased transistor and circuit speeds and improved reliability. Such demands for increased density, performance and reliability require formation of device features with high precision and uniformity.
Conventional semiconductor devices comprise a substrate and various electrically isolated regions, called active regions, in which individual circuit components are formed. The electrical isolation of these active regions is typically accomplished by forming field oxide regions by thermal oxidation of the semiconductor substrate, typically monocrystalline silicon or an epitaxial layer formed thereon, bounding the active regions.
One type of isolation structure is known as trench isolation, wherein shallow trenches are etched in the substrate and an oxide liner is thermally grown on the trench walls. The trench is then refilled with an insulating material. The resulting structure is referred to as a shallow trench isolation (STI) structure. The active region typically comprises source/drain regions formed in the semiconductor substrate by implantation of impurities, spaced apart by a channel region on which a gate electrode is formed with a gate oxide layer therebetween. The gate electrode controls the turn-on and turn-off of each transistor.
A typical method of trench formation comprises initially growing a pad oxide layer on the substrate, and depositing a barrier nitride layer thereon. A photoresist mask is then applied to define the trench areas. The exposed portions of the nitride layer are then etched away, followed by the pad oxide layer. The etching continues into the substrate to form the shallow trench. When etching of the trench is completed, the photoresist is stripped off the nitride layer.
Next, the substrate is oxidized to form an oxide liner on the walls and base of the trench to control the silicon-silicon dioxide interface quality. The trench is then refilled with an insulating material such as silicon dioxide derived from tetraethyl orthosilicate (TEOS) to form a field oxide region. The insulating material is then planarized, as by chemical-mechanical polishing (CMP) using the barrier nitride layer as a polish stop, to remove all the oxide over the active regions so that only the trenches are filled. The nitride and pad oxide are stripped off the active areas to complete the trench isolation structure.
The planarization of the insulating material is a difficult process, because the field oxide regions vary widely in size. For example, one trench may have a width as little as 0.25 &mgr;, while an adjacent trench may be several microns wide. After the insulating material is deposited to fill the trenches and cover the polish stop, fissures called “seams” exist in the deposited insulating material above the smaller trenches, and indentations called “steps” exist in the upper surface of the insulating material above the large trenches. The steps are considerably wider than the seams; however, the seams are considerably deeper than the steps. The presence of both seams and steps is problematic during polishing, in that the greater amount of polishing required to remove the seams over the small features results in the removal of too much insulating material over the large features. This overpolishing of the insulating material above the large trenches produces undesirable “dishing” of the insulating material, resulting in a nonplanar insulating surface.
The problem of simultaneously planarizing an insulating material over both large and small features has been addressed by providing preliminary masking and etching steps, and then polishing, as by CMP. This technique is illustrated in
FIGS. 1A-1C
. Adverting to
FIG. 1A
, there is schematically illustrated the substrate
11
, pad oxide layer
12
, polish stop
13
, oxide liner
14
, trenches
15
, insulating layer
16
, seams
17
and steps
18
. Inverse source/drain photoresist mask
19
is formed on the insulating layer
16
to protect the seams
17
and steps
18
from overetching. Isotropic etching is then performed to remove most of the insulating material in the active areas (
FIG. 1B
) before the final chemical-mechanical polish, as shown in FIG.
1
C.
In principal this works very well. However, as the isotropic etch progresses, the contact area of photoresist mask
19
above small trenches
15
typically narrows down to a point. At this point, photoresist mask
19
detaches from insulating material
16
, and the etch process then attacks seams
17
. Seams
17
tend to be etched at a faster rate, since they are less compact, causing overetching and undesirable indentation around the seam. Ideally, it would be preferred to etch away all of insulating layer
16
on top of polish stop layer
13
, then proceed with CMP to remove the remaining portions of insulating layer
16
(called “fences”) followed by a short polish. However the indentation around seams
17
require a portion of insulating layer
16
be left on top of polish stop layer
13
, so the indentation does not extend below the top surface of polish stop layer
13
. This remaining portion of insulating layer
16
above polish stop layer
13
contributes to increased non-uniformity of the planarized top surface of insulating
16
. Moreover, as minimum device critical dimension (CD) shrinks, indentation of seams
17
happens earlier in the etch process, requiring a higher oxide polish target.
Furthermore, the inverse source/drain mask
19
is a “critical mask”; i.e., it is complex and difficult to design and use. Still further, due to the topography of insulating material layer
16
prior to polishing, a relatively large depth of focus is required to produce mask
19
.
Accordingly, there exists a need for a method of manufacturing a shallow trench isolation structure with improved field oxide planarity without the necessity of employing a complex critical mask.
SUMMARY OF THE INVENTION
An object of the present invention is a method of manufacturing a semiconductor device having insulated trenches formed in a semiconductor substrate, wherein an insulating material which fills the trenches and acts as the field oxide is planarized using a simplified, non-critical inverse source/drain mask.
Additional objects, advantages and other features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from the practice of the invention. The objects and advantages of the invention may be realized and obtained as particularly pointed out in the appended claims.
According to the present invention, the foregoing and other objects are achieved in part by a method of manufacturing a semiconductor device having a plurality of trenches formed in a semiconductor substrate or in an epitaxial layer on the semiconductor substrate, which method comprises: forming a pad oxide layer on a main surface of the substrate or epitaxial layer; forming a polish stop layer having an upper surface on the pad oxide layer; forming a relatively large trench having side surfaces; depositing a first layer of an insulating material to fill the relatively large trench and cover the polish stop layer, whereby the first layer of the insulating material has a step in its upper surface above the relatively large trench; providing a planarization mask on the first layer of the insulating material above the step; etching to remove substantially all of the first layer of the insulating material on the polish stop layer; removing the planarization mask; performing a first polis

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