Separation of rare earth values by liquid/liquid extraction

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Rare earth metal

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423DIG14, 75101BE, C01F 1700

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046474382

ABSTRACT:
At least one rare earth value is selectively separated from at least one other rare earth value, by selectively liquid/liquid extracting an aqueous phase comprising the nitrates of said rare earth values with an organic phase which comprises an organic extractant, said organic extractant comprising at least one organophosphinic compound having one of the formulae (I) or (I'): ##STR1## wherein R.sub.1 and R.sub.2, which may be identical or different, are each substituted or unsubstituted alkyl, cycloalkyl, alkoxyalkyl or alkylcycloalkyl radicals, and X is either hydrogen or a cation.

REFERENCES:
patent: 3966569 (1976-06-01), Reinhardt et al.
patent: 4041125 (1977-08-01), Alstad et al.
patent: 4382016 (1983-05-01), Rickelton et al.
patent: 4461748 (1984-07-01), Sabot et al.
Brown et al, "Proceedings of the 7th Rare Earth Research Conference", vol. 1, Oct. 1968, Coronado, Calif.
Chemical Abstracts, vol. 82, 1975, No. 116863f.
Chemical Abstracts, vol. 81, 1974, No. 180681b.

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