Semiconductor laser structure and method of manufacturing same

Coherent light generators – Particular active media – Semiconductor

Reexamination Certificate

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C372S043010, C372S044010, C372S045013, C372S046012, C372S049010, C372S049010, C372S049010, C372S050121

Reexamination Certificate

active

06775309

ABSTRACT:

The present invention refers to semiconductor lasers and methods of making same.
Exemplary of a prior art semiconductor laser is the arrangement shown in
FIG. 1
, which is currently referred to as a SIBH (Semi-Insulating Buried Heterojunction) structure.
Specifically, in
FIG. 1
reference numeral
1
denotes a n-type substrate defining a mesa like structure laterally confined by an Fe—InP semi-insulating layer
2
. Reference numeral
3
denotes the MQW active (i.e. lasing) layers over which a further p layer
4
and a SiO
2
mask
5
are provided. Finally, reference numeral
6
indicates an n-InP layer superposed to the Fe—InP semi-insulating layers and adjoining the sides of mask
5
as an anti-diffusion layer to prevent Zn—Fe interdiffusion.
The captioned structure is conventional in the art and may be resorted to for manufacturing, i.a. SIBH-DFB (Distributed Feed Back) lasers operating e.g. in the 1.3 micrometer wavelength range.
A problem currently encountered with such structures is that, while being fully effective at room temperature (or lower), at higher temperatures (around 80° C. or above) the semi-insulating behavior of the Fe—InP layers is no longer satisfactory. This is essentially due to a fairly large leakage current being established across the Fe—InP regions.
Furthermore, since the Fe—InP layers are in contact with the MQW active layers, the Fe atoms will diffuse into the MQW layers and the p-InP layer (denoted
4
in
FIG. 1
) located above the MQW layers. This results both in reduced reliability and in high series resistance. Specifically, a 0.2-0.3 micrometer diffusion region of Fe into the MQW region can be observed by low temperature cathode luminescence. Also, a 0.2-0.3 equivalent reduction of the p-InP width (layer
4
) caused by Fe—Zn interdiffusion can be detected by series resistance measurements.
In order to reduce the leakage current, an alternative SIBH structure has been proposed where a wide-bandgap layer is arranged between the original mesa arrangement and the semi-insulating layer: see S. Asada et al., “Analysis of Leakage Current in Buried Heterostructure Lasers with Semiinsulating Blocking Layers”, IEEE Journal of Quantum Electronics, Vol. 25, No. 6, June 1989, pp. 1362-1368.
The leakage current can thus be greatly reduced due to a large turn-on voltage of the wide-bandgap material (e.g. a thin InGaP layer).
The main disadvantage of that arrangement is related in the growth of the wide-bandgap layer by means of MOCVD (Metal Organic Chemical Vapor Deposition). The high mismatch between InP and InGaP does not in fact permit an InGaP layer to be grown even in the range of 100 nanometers, which causes reliability deterioration under high temperature working conditions.
The object of the present invention is thus to provide a further improved solution overcoming the disadvantages outlined in the foregoing.
According to the present invention, that object is achieved by means of a semiconductor laser structure having the features called for in the annexed claims. The invention also relates to the corresponding manufacturing method.


REFERENCES:
patent: 4829347 (1989-05-01), Cheng et al.
patent: 5325385 (1994-06-01), Kasukawa et al.
patent: 5400355 (1995-03-01), Ishida
patent: 5696389 (1997-12-01), Ishikawa et al.
patent: 5822349 (1998-10-01), Takaoka et al.
patent: 6030452 (2000-02-01), Takeuchi
patent: 6198863 (2001-03-01), Lealman et al.
patent: 6437372 (2002-08-01), Geva et al.
patent: 6542525 (2003-04-01), Matsumoto et al.
patent: 6556605 (2003-04-01), Shtengel et al.
Patent Abstracts of Japan Publication No. 09214045, Publication Date Aug. 15, 1997.
Patent Abstracts of Japan Publication No. 2000216500, Publication Date Aug. 4, 2000.
“Chromium-doped semi-insulating InP grown by metalorganic vapour phase epitaxy”, M.J. Harlow, W.J. Duncan, I. F. Lealman, P.C. Spurdens*.
“Analysis of Leakage Current in Buried Heterostructure Lasers with Semiinsulating Blocking Layers” Susumu Asada, Shigeo Sugou, Ken-Ichi Kasahara, and Shigetaka Kumashiro.

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