Semiconductor device with a copper barrier layer and formation t

Active solid-state devices (e.g. – transistors – solid-state diode – Combined with electrical contact or lead – Of specified material other than unalloyed aluminum

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257740, 257741, 257750, 257757, 257762, 257768, 438595, 438627, 438643, 438653, 438682, 438687, H01L 2972

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active

060939664

ABSTRACT:
A method of forming a semiconductor device by first providing a substrate in a processing chamber. The substrate has an insulating layer and an opening in the insulating layer. A copper barrier layer is formed on the insulating layer and in the opening by providing a plurality of refractory metal atoms and a plurality of silicon atoms in the processing chamber. The atoms are ionized by applying a first bias to the atoms to form a plasma. The substrate is then biased by a first stage bias followed by a second stage bias to accelerate the plasma to the substrate to form the copper barrier layer, where the first stage bias is less than the second stage bias. The copper-containing metal is then deposited on the copper barrier layer over the insulating layer and in the opening. The present invention further includes a semiconductor device formed by the above method.

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patent: 5449955 (1995-09-01), Debiec et al.
patent: 5614437 (1997-03-01), Choudhury
"Metal Ion Deposition From Ionized Mangetron Sputtering Discharge," Rossnagel, et al.; J. Vac. Sci. Technol. B 12(1), Jan./Feb. 1994; pp. 449-453.
"Filling Dual Damascene Interconnect Structures With AICu and Cu Using Ionized Magnetron Deposition," Rossnagel; J. Vac. Sci. Technol. B 13(1), Jan./Feb. 1995; pp. 125-129.
"Simulations of Trench-Filling Profiles Under Ionized Magnetron Sputter Metal Deposition," Hamaguchi, et al., Mar. 20, 1998.

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