Semiconductor device having shallow trench isolation structure

Active solid-state devices (e.g. – transistors – solid-state diode – Integrated circuit structure with electrically isolated... – Including dielectric isolation means

Reexamination Certificate

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C438S424000, C438S437000

Reexamination Certificate

active

06670689

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device having a shallow trench isolation (hereinafter, referred to as STI) structure and a method for manufacturing the same.
2. Description of the Related Art
Much progress has been made in increasing speed and integration of semiconductor devices. Along with this progress, higher-density patterns and reduction in size has become increasingly important. Wide isolation regions in semiconductor devices have also made higher-density patterns and reduced sizes a requirement.
Local oxidation of silicon (LOCOS) layers have been mainly used as conventional isolation layers of semiconductor devices. However, bird's beak configurations are created at the edges of the isolation layer by the LOCOS method and thus the area of active regions is reduced and current leakage occurs.
Recently, shallow trench isolation (STI) layers having narrow widths and excellent isolation characteristics have been proposed and a semiconductor device having such STI structure will be described with reference to FIG.
1
.
Referring to
FIG. 1
, a blocking pattern (not shown) is formed on a semiconductor substrate
10
to expose an isolation region. The semiconductor substrate
10
can be defined as a cell area, a core area and a peripheral area. In addition, the blocking pattern may be a stack of an oxide layer and a silicon nitride layer. The exposed semiconductor substrate
10
is etched to a predetermined depth using the blocking pattern as a mask, thereby forming trenches t
1
and t
2
therein. The trench t
1
is formed in the cell area and the trench t
2
defines a P-channel field effect transistor (P-FET) area in the core or peripheral areas. A dry etching process is performed for forming the trenches t
1
and t
2
using a plasma.
The dry etching process for forming the trenches t
1
and t
2
, however, may cause silicon lattice defects and damage inner surfaces of the trenches t
1
and t
2
. Conventionally, to reduce such silicon lattice defects and damage, a sidewall oxide layer
12
is formed by thermally oxidizing the inner surfaces of the trenches t
1
and t
2
. Also, the formation of a sidewall oxide layer
12
smoothens sharp corners of the trenches t
1
and t
2
.
Afterwards, a silicon nitride liner
14
is formed on the surface of the sidewall oxide layer
12
. As is well known, the silicon nitride liner
14
prevents the generation of stress caused by the coefficient of thermal expansion (CTE) mismatch between the semiconductor substrate
10
formed of silicon and a silicon oxide layer with which the trenches t
1
and t
2
will be filled.
A dielectric material, for example, a high-density-plasma (HDP) dielectric layer is deposited over the resultant semiconductor substrate
10
to completely fill the trenches t
1
and t
2
. Next, chemical mechanical polishing (hereinafter, referred to as “CMP”) is performed on the HDP dielectric layer and the blocking pattern to expose the surface of the semiconductor substrate
10
. This completes the formation of an STI layer
16
.
However, semiconductor devices having the conventional STI structure causes the following problems. With reference to
FIGS. 2A and 2B
, since hot carriers of a highly integrated semiconductor MOS transistor generally have high energy, they bounce to a thin gate oxide layer
22
or easily penetrate through the sidewall oxide layer
12
into the STI layer
16
. The hot carriers penetrating into the STI layer
16
are mainly negative charges, namely, electrons
30
, which are easily trapped in the silicon nitride liner
14
in the STI layer
16
and on the interface between the silicon nitride liner
14
and the sidewall oxide layer
12
. At this time, the electrons
30
are closely trapped since the sidewall oxide layer
12
is remarkably thin as described above. In the case where the electrons
30
are dense with the edge of the STI layer
16
, positive charges of the semiconductor substrate
10
on which MOS transistors are formed, namely, holes
32
are induced to the circumference of the STI layer
16
. At this time, since the electrons
30
are closely trapped in the silicon nitride liner
14
and on the interface between the silicon nitride liner
14
and the sidewall oxide layer
12
, the holes
32
in the semiconductor substrate
10
are densely gathered together.
As shown in
FIG. 2A
since in an N-channel field effect transistor (N-FET) major carriers are the electrons
30
, a path is not formed between n-type junction areas
26
a
and
26
b
in which the electrons
30
function as major carriers even though the holes
32
are dense with the circumference of the STI layer
16
.
As is well known, since, in a P-FET, major carriers are the holes
32
, as shown in
FIG. 2B
, the holes
32
, which are densely populated at the circumference of the STI layer
16
, form a current path I connecting p-type junction areas
28
a
and
28
b
isolated by the STI layer
16
. Consequently, due to the current path I, although p-type junction areas
28
a
and
28
b
are isolated by the STI layer
16
, leakage current, such as abnormally increased standby current after burn-in, occurs between adjacent P-FETs, thereby deteriorating the characteristics of the P-FETS. Here, reference numeral
24
denotes a gate electrode of a MOSFET.
Furthermore, if a P-FET (not shown) is on the interface between the STI layer
16
and an active region, a channel area of the P-FET abuts the silicon nitride liner
14
, in which the electrons are trapped, by the thin sidewall oxide layer
12
. Consequently, the electrons trapped in the silicon nitride liner
14
easily induce holes to the channel area of the P-FET in the interface. Also, the holes induced in turning on the P-FET are not easily removed and remain when turning off the P-FET. Thus, the length of the channel of the P-FET on the interface is gradually reduced, thereby decreasing threshold voltage and breakdown voltage. Consequently, the characteristics of the P-FET are undesirably altered.
SUMMARY OF THE INVENTION
To solve the above problems, the present invention provides a semiconductor device having a shallow trench isolation (STI) structure, which can reduce leakage current of the semiconductor device around an STI layer.
The present invention also provides a method of manufacturing of the semiconductor device having the STI structure.
According to a first embodiment of the present invention, the semiconductor device having an STI structure includes a semiconductor substrate having a plurality of trenches providing isolation in a cell area in which memory devices are formed, and in non-cell areas, e.g., core or peripheral areas in which P-FETs and other circuit devices are formed. A first sidewall oxide layer is formed on the inner surfaces of the plurality of trenches. A second sidewall oxide layer is formed on first sidewall oxide layer in one or more of the plurality of trenches in the non-cell areas. A first relief liner is formed on the first sidewall oxide layer in one or more of the plurality of trenches in the cell area. A second relief liner is formed on the first relief liner and also on the second sidewall oxide layer. The plurality of trenches are filled with a dielectric material.
According to a second embodiment of the present invention, the semiconductor device having an STI structure includes a semiconductor substrate having a plurality of trenches for isolating a cell area in which memory devices are formed and core or peripheral areas in which a P-FET and other circuit devices are formed and between devices formed in respective areas. A first sidewall oxide layer is formed on the inner surfaces of the plurality of trenches. A second sidewall oxide layer is formed on the first sidewall oxide layer in one or more of the plurality of trenches isolating between P-FETs in the core or peripheral areas. A first relief liner is formed on the first sidewall oxide layer in one or more of the plurality of trenches isolating between memory devices in the cell area and between the othe

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