Semiconductor device and process for fabricating the same

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S303000, C257S306000, C257S308000, C257S309000, C257S532000, C257S637000

Reexamination Certificate

active

06459112

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to a semiconductor device and a process for fabricating the same, more specifically to a semiconductor device including capacitors and a process for fabricating the same.
A dynamic random access memory (DRAM) comprises memory cells each including one transfer transistor and one capacitor, which allows the DRAM to have a small area. This makes the DRAM a semiconductor device suitable for larger capacities. Because of the recent increased amounts of information processing of electronic devices, etc., DRAMS to be used in the electronic devices, etc. are required to be further micronized and have larger capacities. A DRAM having the cylindrical capacitors which will be described below are used.
A process for fabricating the conventional DRAM will be explained with reference to
FIGS. 15A
to
17
. In
FIGS. 15A
to
17
, the views on the left sides of the drawings are sectional views of the DRAM along a bit line, and sectional views of the DRAM along a word line are shown on the right sides of the drawings.
A device isolation film
112
is formed on the surface of a silicon substrate
110
by LOCOS (LOCal Oxidation of Silicon). Then, a gate oxide film (not shown) is formed on the surface of the silicon substrate
110
. Next, a polysilicon film
114
, a tungsten silicide film
116
, a silicon oxide film
118
, a silicon nitride film
120
and a silicon nitride oxide film
122
are sequentially formed on the entire surface by CVD (Chemical Vapor Deposition) to form a layer film
123
of these films.
Then, the layer film
123
is patterned into a prescribed shape to form gate electrodes
124
of the polycide structure of the polysilicon film
114
and the tungsten silicide film
116
. The gate electrodes
124
function as the word lines also functioning as the gate electrodes of other transfer transistors extended vertically as viewed in the drawing on the left side of FIG.
15
A.
Dopant ions are implanted in the silicon substrate
110
with the layer film
123
as a mask to form a source/drain diffused layer
126
a
,
126
b
by self-alignment with the layer film
123
. Next, a silicon nitride film is formed on the entire surface and is subjected to anisotropic etching until the surfaces of the silicon substrate
110
, the device isolation film
112
and the layer film
123
to form a sidewall insulation film
128
on the sidewalls of the layer film. The sidewall insulation film
128
is for forming an SAC (Self Aligned Contact) for ensuring a large margin for shift of the micronized contact. Then, an etching stopper film
130
of the silicon nitride film is formed on the entire surface.
Then, an inter-layer insulation film
132
of an about 0.5 &mgr;m-thickness BPSG (Boro-Phospho-Silicate Glass) film is formed by CVD. Then, the surface of the inter-layer insulation film
132
is planarized by reflow and CMP (Chemical Mechanical Polishing). Next, contact holes
134
for exposing the source/drain diffused layer
126
b
are formed by self-alignment with the sidewall insulation film
128
. Then, conductor plugs
136
a
are formed in the contact holes
134
(see FIG.
5
A).
Next, an about 0.1 &mgr;m-thickness silicon oxide film
138
is formed on the entire surface by CVD. Next, contact holes
140
for exposing the source/drain diffused layer
126
a
are formed by self-alignment with the sidewall insulation film
128
. Then, a polysilicon film
142
, a tungsten silicide film
144
, a silicon oxide film
146
, a silicon nitride film
148
and a silicon nitride oxide film
150
are sequentially formed by CVD on the entire surface to form a layer film
152
of these films. Then, the layer film
152
is patterned into a prescribed shape to form bit lines
154
of the polycide structure of the polysilicon film
142
and the tungsten silicide film
144
(FIG.
15
B).
Next, a silicon nitride film is formed on the entire surface and is subjected to anisotropic etching until the surfaces of the silicon oxide film
138
and the layer film
152
are exposed, whereby a sidewall insulation film
156
is formed on the sidewalls of the layer film
152
. Next, an inter-layer insulation film
160
is formed on the entire surface. Then, the surface of the inter-layer insulation film
160
is planarized by CMP. Then, an etching stopper film
161
of silicon nitride film is formed on the inter-layer insulation film
160
by CVD. Then, contact holes
162
for exposing the upper surfaces of the conductor plugs
136
a
are formed. Next, conductor plugs
136
b
are formed in the contact holes
162
(see FIG.
16
A).
Next, an about 1.7 &mgr;m-thickness BPSG film
164
is formed on the entire surface by CVD. Then, openings
166
for exposing the upper surfaces of the conductor plugs
136
b
are formed in the BPSG film
164
. The openings
166
are for forming storage electrodes
168
(see
FIG. 17
) of capacitors
179
in a later step (FIG.
16
B).
Next, an about 0.05 &mgr;m-thickness polysilicon film is formed on the entire surface by CVD. Next, a resist film not shown is applied to the entire surface. Then, the polysilicon film and the resist film are polished by CMP until the surface of the BPSG film
164
is exposed. The storage electrodes
168
of the polysilicon film are formed inside the openings
166
. Next, the BPSG film
164
is removed by HF-based wet etching with the etching stopper film
161
as a stopper.
Then, the resist film left on the inside of the storage electrodes
168
is removed by ashing. Next, an about 8 nm-thickness tantalum oxide film
172
is formed on the entire surface by CVD. The tantalum oxide film
172
functions as a dielectric of the capacitors
179
. Next, a 0.05 &mgr;m-thickness titanium nitride film
174
and a 0.1 &mgr;m-thickness polysilicon film
176
are sequentially formed by CVD to form an opposed electrode
177
of the capacitors (see FIG.
17
).
However, in the conventional DRAM fabrication process, when the BPSG film
164
is HF-based wet etching, it is often a case that the storage electrodes
168
are adversely peeled off the conductor plug
136
b
, or the etchant permeates near the upper surfaces of the conductor plugs
136
b
to adversely etch regions which should not be etched. This lowers yields of the DRAM.
In micronizing the DRAM it is necessary to increase a height of the capacitors so as to maintain substantially the same capacity of the capacitors. As a result, steps between each cell and its adjacent one is larger, which makes the formation of the contact holes and wirings difficult.
In the process for fabricating the conventional DRAM, a space must be ensured for the contacts between the gate electrodes of the transistors of peripheral circuits and the upper wirings, which hinders further micronization of the DRAM.
In the process for fabricating the conventional DRAM, the bit lines
154
are covered with a thick silicon nitride film of the high dielectric constant, which results in large parasitic capacities.
SUMMARY OF THE INVENTION
A first object of the present invention is to provide a semiconductor device and a process for fabricating the semiconductor device which can fabricate at high yields the semiconductor device even including cylindrical capacitors. A second object of the present invention is to provide a semiconductor device and a process for fabricating the semiconductor device which can realize space-savings for peripheral circuits. A third object of the present invention is to provide a semiconductor device and a process for fabricating the semiconductor device which can fabricate the semiconductor device having small parasitic capacities between the bit lines and the conductor plugs.
The above-described objects are achieved by a semiconductor device comprising: a first insulation film formed above a base substrate; a second insulation film formed on the first insulation film and having different etching characteristics from the first insulation film; and a capacitor including a storage electrode formed on the second insulation film, projected therefrom, the storage electrode being

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