Semiconductor device and method of manufacturing the same

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S303000, C257S306000, C438S244000, C438S243000, C438S253000, C438S387000

Reexamination Certificate

active

06583461

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and a method of manufacturing it, and more particularly to a semiconductor device provided with a capacitor having a large capacitance in a form that the surface area of an opening where a capacitor electrode is formed is increased, and a method of manufacturing such a semiconductor device.
2. Description of the Related Art
The semiconductor device having a capacitor such as DRAM has a problem that a capacity of the capacitor decreases with development of downsizing of an element. In recent years, in order to solve this problem, various capacitors have been proposed. One of them is a cylindrical capacitor.
FIGS. 29A and 29B
are a sectional view and a plan view each showing a part of a conventional semiconductor device having the cylindrical capacitor.
Referring to
FIG. 29
, a gate wiring(s)
103
is formed on a semiconductor substrate
101
through a gate insulating film not shown. On the upper surface and side surface of the gate wiring
103
, a silicon oxide film
105
and a nitride film side wall
107
are formed, respectively. Further, on the oxide film
105
, a nitride film
109
is formed as an etching stopper film. On the gate wiring
103
, an insulating film
111
having an opening(s)
113
which reaches the semiconductor substrate
101
is formed through these insulating film. The openings
113
are filled with conductive layers
115
and
116
which are electrically connected to the semiconductor substrate
101
.
On the insulating film
111
, an interlayer insulating film
121
including a bit wiring
125
is formed. In the interlayer insulating film
121
, an opening(s)
123
communicating with the openings
113
is formed. The opening
123
is filled with a bit wiring
125
which is connected to the semiconductor substrate
101
through the conductive layer
115
. An opening
135
is formed to passe through between the bit wirings
125
and to communicate with the opening
113
. The opening
135
is filled with a conductive layer
137
which is connected with the semiconductor substrate
101
through the conductive layer
116
.
On the interlayer insulating film
121
, an interlayer insulating film
139
having a cylindrical opening
143
communicating with the opening
135
is formed. Within the opening
143
, a cylindrical capacitor
159
is formed along inner wall of the cylindrical opening
143
. The cylindrical capacitor
159
includes a capacitor lower electrode
152
, a capacitor dielectric film
154
and a capacitor upper electrode
156
. The capacitor
159
is electrically connected to the semiconductor substrate
101
through the conductive layer
137
and the conductive layer
116
.
Referring to sectional views showing a manufacturing process in
FIGS. 30
to
38
, an explanation will be given of a method of manufacturing the semiconductor device described above.
First, referring to
FIG. 30
, on a semiconductor substrate
101
, gate wirings
103
each covered with an oxide film
105
as a hard mask is formed. A side wall film
107
made of a nitride film is formed on a side surfaces of the gate wirings
103
. On the gate wirings
103
, an etching stopper
109
made of a nitride film and an insulating film
111
made of an oxide film are formed successively.
Referring to
FIG. 31
, using a resist film
113
as a mask, the insulating film
111
and etching stopper
109
are etched to expose the semiconductor substrate
101
so that openings
113
are formed.
In this case, owing to this etching, a modified layer is formed on the surface of the semiconductor substrate
101
. This modified layer is removed by dry etching.
Referring to
FIG. 32
, a conductive layer
115
is formed within each of the openings
113
by etch-back technique or CMP (Chemical Mechanical Polishing) technique.
Referring to
FIG. 33
, an insulating film
118
made of an oxide film is formed on the insulating film
111
. On the insulating film
118
, a resist film
173
having a desired pattern is formed. Thereafter, using the resist film
173
as a mask, the insulating film
118
is etched to make an opening
123
which reaches the conductive layer
115
.
In this case, since a modified layer due to the dry etching is formed on a surface of the conductive layer
115
within the opening
123
, this modified layer is removed by dry etching.
Referring to
FIG. 34
, a bit wiring
125
is formed on the insulating film
118
so as to be embedded in the opening
123
.
Referring to
FIG. 35
, an insulating film
120
made of an oxide film is formed on the bit wiring
125
. A resist film
183
having a desired pattern is formed on the insulating film
120
. Thereafter, using the resist film
183
as a mask, an interlayer insulating film
121
including the insulating films
120
and
118
is etched to form an opening
135
which reaches the conductive layer
116
. In this case, since the modified layer due to the etching is formed on a surface of the conductive layer
116
, the modified layer is removed by the dry etching.
Referring to
FIG. 36
, a conductive layer
137
is formed within the opening
135
by the etch-back technique or CMP technique.
Referring to
FIG. 37
, an interlayer insulating film
139
is formed on the interlayer insulating film
121
. Further, a resist film
177
having a desired pattern is formed on the interlayer insulating film
139
. Thereafter, using the resist film
177
as a mask, the interlayer insulating film
139
is etched to form a cylindrical opening
143
which reaches the conductive layer
137
. In this case, since the modified layer due to the etching is formed on a surface of the conductive layer
137
, the modified layer is removed by the dry etching.
Referring to
FIG. 38
, a polysilicon film
151
, oxide
itride film
153
and polysilicon film
155
are formed on the interlayer insulating film
139
and along the inner wall of the cylindrical opening
143
.
Finally, referring to
FIG. 29
again, the polysilicon film
151
, oxide
itride film
153
and polysilicon film
155
which are located on the insulating film
139
are removed by the etch-back technique or CMP technique. Thus, a capacitor
159
which comprises the capacitor lower electrode
152
, capacitor dielectric film
154
and a capacitor upper electrode
156
is formed to complete a semiconductor device.
However, in the above described conventional technique, when downsizing further proceeds, the cylindrical opening may be deepened in order to assure a necessary capacitance. This makes it very difficult to form the cylindrical opening. In addition, it is difficult to remove completely the modified layer produced due to etching to form the opening. The residue provides an increased contact resistance which leads to reduction of a response speed of the device.
SUMMARY OF THE INVENTION
The present invention has been accomplished to solve the problems described above.
A first object of the invention is to provide a semiconductor device which can increase the area of a capacitor electrode without greatly changing a conventional structure, thereby assuring sufficient capacitance of a capacitor.
A second object of the invention is to provide a semiconductor device which reduces the resistance between a capacitor electrode and a semiconductor substrate and have great reliability in electricity.
A third object of the invention is to provide a method of manufacturing the above described semiconductor device.
The semiconductor device having a capacitor, comprises:
a semiconductor substrate;
a plurality of insulating layers formed on the semiconductor substrate;
a plurality of openings formed in each of the insulating layer so as to communicate with one another, the openings having different diameters at least at each of coupling portions;
a conductive layer formed partially or substantially entirely in the opening in a lowermost layer of the multi-layer insulating layers in contact with the semiconductor substrate, and the conductive layer electrically connected to the semiconductor substra

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