Semiconductor device and method for manufacturing same

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S672000

Reexamination Certificate

active

07867906

ABSTRACT:
A trench is formed in an insulation film formed on top of a semiconductor substrate, and a barrier metal film is formed on the surface of the trench. After a copper or copper alloy film is formed on the barrier metal film, an oxygen absorption film in which a standard energy of formation of an oxidation reaction in a range from room temperature to 400° C. is negative, and in which an absolute value of the standard energy of formation is larger than that of the barrier metal film is formed, and the assembly is heated in a temperature range of 200 to 400° C. A semiconductor device can thereby be provided that has highly reliable wiring, in which the adhesion to the barrier metal film in the copper interface is enhanced, copper diffusion in the interface is suppressed, and electromigration and stress migration are prevented.

REFERENCES:
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patent: 2004/0000719 (2004-01-01), Matsubara et al.
patent: 2004/0087078 (2004-05-01), Agarwala et al.
patent: 2006/0255463 (2006-11-01), Won
patent: 2009/0305498 (2009-12-01), Streck et al.
patent: 2010/0181682 (2010-07-01), Arai
patent: 09-289214 (1997-11-01), None
patent: 2003-332426 (2003-11-01), None
patent: 2004-031847 (2004-01-01), None
patent: 2004/053971 (2004-06-01), None
patent: 2004/061931 (2004-07-01), None
International Search Report of PCT/JP2006/310253 filed May 23, 2006, date of mailing Aug. 22, 2006.

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