Selective removal of TixNy

Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching

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438730, 438738, H01L 2100

Patent

active

059487020

ABSTRACT:
A dry etch method for removing TixNy films by using a remote plasma to excite a oxygen+fluorine source gas mixture, generating active species that etch TixNy with minimum attack to other materials. In particular, an isotropic dry etch can be used for the selective removal of TiN in W/TiN gate structures without gate oxide damage. This etch also permits selective stripping of titanium nitride in a salicidation process.

REFERENCES:
patent: 5108542 (1992-04-01), Lin
patent: 5846880 (1998-12-01), Lee
patent: 5866484 (1999-02-01), Muto
Cotler, et al., "Plasma-Etch Technology", (Jul. 1990) IEEE Circuits and Devices Magazine, pp. 38-43.
Pearton, et al., "Hybrid Electron Cyclotron Resonance-RF Plasma Etching of TiN.sub.x Thin Films Grown by Low Pressure Rapid Thermal Metalorganic Chemical Vapour Deposition", Semiconductor Science and Technology (1991), pp. 830-832.

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