Selective isomerization and linear dimerization of olefins...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S169000, C526S171000, C526S172000, C526S161000, C526S901000, C526S130000

Reexamination Certificate

active

07001964

ABSTRACT:
Provided herein is an oligomerization product formed from alpha-olefins having at least three carbon atoms comprising dimers, at least about 80 weight percent of which are linear. In an embodiment, an oligomerization product formed from alpha-olefins having at least three carbon atoms comprises trimers, at least about 20 weight percent of which are linear. In another embodiment, an oligomerization product formed from alpha-olefins having at least three carbon atoms comprises tetramers, at least about 5 weight percent of which are linear. In yet another embodiment, an oligomerization product formed from alpha-olefins having at least three carbon atoms comprises pentamers, at least about 5 weight percent of which are linear.

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patent: 6103946 (2000-08-01), Brookhart, III et al.
patent: 6291733 (2001-09-01), Small et al.
patent: 6489497 (2002-12-01), Brookhart, III et al.
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patent: 1124123 (1968-08-01), None
patent: 1129463 (1968-10-01), None
Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene, Brooke L. Small, Maurice Brookhart, and Alison M.A. Bennett,Journal of the American Chemical Society, vol., 120, No. 16, Pp. 4049-4050, 1998.
Iron Catalysts for the Head-to-Head Dimerization of a-Olefins and Mechanistic Implications for the Production of Linear a-Olefins, Brooke L. Small and A.J. Marcucci,Organometallics, vol. 20, No. 26, Pp. 5738-5744, 2001.
International Search Report, PCT/US 03/29158, Feb. 23, 2004; 3 pages.

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