Seeded porous copolymers and ion-exchange resins prepared theref

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

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521 25, 521 30, 521 31, 526201, 526203, 526318, 52631825, 526319, 526336, 526340, 526347, C08J 520

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active

052311155

ABSTRACT:
The invention concerns preparation of porous copolymer beads by a seeded polymerization process employing gel copolymer seed particles. The process comprises initially providing a plurality of gel-type copolymer seed particles prepared by polymerization of at least one first monovinylidene monomer and a first cross-linking monomer. A second monomer mixture comprising at least one second monovinylidene monomer, a second cross-linking monomer, and a phase-separating diluent is thereafter imbibed by the seed particles and polymerized therein. The process is characterized by selecting the first monovinylidene monomers such that the phase-separating diluent and second monovinylidene monomers are capable of being imbibed by the seed particles in an amount sufficient to form a porous copolymer. The porous copolymer beads produced have stable polymeric structures and good physical properties that render them useful in preparing ion-exchange resins and polymeric adsorbents.

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